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WATER-ERASABLE FIRED PENCIL LEAD AND ERASION OF LINE DRAWN WITH THE SAME

机译:水性可燃铅笔芯和相同线的拉丝

摘要

PROBLEM TO BE SOLVED: To provide a water-erasable fired pencil lead and a method of erasing lines drawn therewith. ;SOLUTION: Boron nitride and an auxiliary binder for molding (an organic polymer) are kneaded, extrusion-molded and fired in a non-oxidative atmosphere to prepare the first fired lead comprising a carbide formed by carbonization of the binder and boron nitride. Then, the first fired lead is heated in an oxidative atmosphere to oxidatively remove the binder as a carbide to give a second fired lead comprising boron nitride. The second fired lead is impregnated with a perhydropoly-silazane-containing solution to fill the pores in the lead. The impregnated lead is heat-treated in an inert atmosphere to form silicon nitride whereby a third fired white lead comprising boron nitride and silicon nitride is obtained. The fired white lead is filled with a coloring composition comprising an electron-donating colorless dye, a metallic salt of a phenolic hydroxy group-bearing compound as a color developer of the dye and a nonvolatile compound desensitizing the color-developing reaction whereby the objective water-erasable fired pencil lead is obtained. The line drawn with this pencil can be erased with water.;COPYRIGHT: (C)1997,JPO
机译:要解决的问题:提供一种水溶性烧成的铅笔芯和一种擦除由此绘制的线条的方法。溶液:将氮化硼和用于成型的辅助粘合剂(一种有机聚合物)在非氧化性气氛中捏合,挤压成型并烧制,以制备第一烧制铅,该第一烧制铅包含通过粘合剂和氮化硼碳化而形成的碳化物。然后,将第一烧成铅在氧化性气氛中加热以氧化除去作为碳化物的粘合剂,从而得到包含氮化硼的第二烧成铅。第二个烧成的铅浸有含全氢聚硅氮烷的溶液,以填充铅中的孔。在惰性气氛中对浸渍的铅进行热处理以形成氮化硅,从而获得包含氮化硼和氮化硅的第三烧成的白色铅。烧成的白铅填充有着色组合物,该着色组合物包含给电子无色染料,作为该染料的显色剂的带有酚羟基的化合物的金属盐和对显色反应不敏感的非挥发性化合物,从而使目标水-获得可擦除的烧制铅笔芯。用这支铅笔画的线可以用水擦除。版权所有:(C)1997,JPO

著录项

  • 公开/公告号JPH09286946A

    专利类型

  • 公开/公告日1997-11-04

    原文格式PDF

  • 申请/专利权人 MITSUBISHI PENCIL CO LTD;

    申请/专利号JP19960100267

  • 发明设计人 KITAZAWA KATSUNORI;HOSHIBA MASAAKI;

    申请日1996-04-22

  • 分类号C09D13/00;B43K19/02;

  • 国家 JP

  • 入库时间 2022-08-22 03:32:48

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