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ACTIVE ENERGY BEAM CURING TYPE RESIN COMPOSITION, ITS CURED PRODUCT AND FRESNEL LENS
ACTIVE ENERGY BEAM CURING TYPE RESIN COMPOSITION, ITS CURED PRODUCT AND FRESNEL LENS
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机译:活性能量束固化型树脂组合物,固化产物和菲涅耳透镜
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摘要
PROBLEM TO BE SOLVED: To obtain the subject composition containing a specific urethane acrylate, capable of providing high refractive index type cured coating film excellent in coating workability, physical properties of coating film and economical efficiency, compared with a conventional composition and therefore suitable as a raw material for thin fresnel lens. ;SOLUTION: This compound contains a urethane acrylate comprising (A) an organic isocyanate having two or more isocyanate groups capable of reacting with hydroxy groups (preferably tolylene diisocyanate), (B) a polyol having two or more hydroxyl groups and ≥300 molecular weight (preferably polycaprolactone) and (C) a (meth)acrylate monomer having both of hydroxyl group and aromatic ring. A compound of formula I [R1 is H or methyl; R2 is H or a 1-10C alkyl; R3 to R5 are each H, phenyl, etc.; (a) is 0-20] etc., is preferably used as the component C. Furthermore, the composition is preferably further blended with a compound of formula II [* exhibits an (un)saturation; R6 and R7 are H or a lower alkyl; R8 and R9 are each H or methyl; (n) is 1-10].;COPYRIGHT: (C)1997,JPO
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机译:解决的问题:与常规组合物相比,获得包含特定氨基甲酸酯丙烯酸酯的主题组合物,该主题组合物能够提供在涂布加工性,涂膜的物理性质和经济效率方面优异的高折射率型固化涂膜。菲涅尔透镜的原料。 ;解决方案:该化合物含有氨基甲酸酯丙烯酸酯,该丙烯酸酯包含(A)具有两个或更多个能够与羟基反应的异氰酸酯基的有机异氰酸酯(最好是甲苯二异氰酸酯),(B)具有两个或更多个羟基且分子量≥300的多元醇(优选聚己内酯)和(C)具有羟基和芳族环的(甲基)丙烯酸酯单体。式I化合物[R 1 Sup>为H或甲基; R 2 Sup>为H或1-10C烷基; R 3 Sup>至R 5 Sup>分别为H,苯基等; (C)优选使用(a)为0〜20]等。此外,优选进一步将组合物与式II的化合物[*显示(不)饱和)混合。 R 6 Sup>和R 7 Sup>是H或低级烷基; R 8 Sup>和R 9 Sup>分别为H或甲基; (n)是1-10] 。;版权:(C)1997,日本特许厅
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