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1,2 - jihidorokinokisarin - 2 - on

机译:1,2-吉可怕的Kisarin-2-开

摘要

NEW MATERIAL:A compound expressed by formula I (R1 is carbamoyl or nitrogen-containing 5-membered heterocyclic ring group; R2 is aromatic group; R3 and R4 are alkyl; R5 is alkyl, alkoxy or acylamino; n is 0-2). USE:Yellow dye used as a dye for photograph, dye for ink jet, dye for printing, dye for filter, etc., and having high molar absorption coefficient and sharp absorption characteristics. PREPARATION:A compound expressed by formula II is reacted with an oxidizing agent (e.g. ammonium persulfate) and then subjected to coupling reaction with a compound expressed by formula III and immediately subjected to ring- closing reaction to provide the compound expressed by formula I. The above-- mentioned reaction is carried out in the presence of a base (e.g. sodium carbonate) in a solvent such as N,N-dimethylformamide.
机译:新材料:由式I表示的化合物(R1是氨基甲酰基或含氮5元杂环基; R2是芳族基团; R3和R4是烷基; R5是烷基,烷氧基或酰基氨基; n是0-2)。用途:用作照片染料,喷墨染料,印刷染料,滤光片染料等的黄色染料,具有较高的摩尔吸收系数和鲜明的吸收特性。制备:使式II所示的化合物与氧化剂(例如过硫酸铵)反应,然后与式III所示的化合物进行偶联反应,然后立即进行闭环反应以提供式I所示的化合物。上述反应是在碱(例如碳酸钠)的存在下,在溶剂如N,N-二甲基甲酰胺中进行的。

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