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CYANOACRYLATE ADHESIVES WITH IMPROVED THERMAL PROPERTIES IN HARDENED CONDITION CONTAINING A SUBSTITUTED AROMATIC COMPOUND
CYANOACRYLATE ADHESIVES WITH IMPROVED THERMAL PROPERTIES IN HARDENED CONDITION CONTAINING A SUBSTITUTED AROMATIC COMPOUND
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机译:在含有取代的芳香族化合物的硬化条件下,热性能得到改善的氰基丙烯酸酯粘合剂
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摘要
A cyanoacrylate monomer adhesive formulation which has improved thermal properties resulting from the inclusion in the formulation of an effective amount for enhancing the thermal resistance of the cured polymer of a mono, poly or hetero aromatic compound characterized by at least three substitutions on an aromatic ring thereof, two or more of said substitutions being electron withdrawing groups selected from the group consisting of NO2, CN, CF3, NR13+, SR12+, C(=O)R1, C(=O)OR1, NO, CCl3, SO2, S(=O), SO3, SO2R1, SO2OR1 and F, one or more of said substitutions being leaving groups selected from the group consisting of F, Br, Cl, I, NO2, CN, SOR1, SO2R1 and SO2OR1, and R1 is an optionally substituted hydrocarbon group. Example such compounds have the formula: CHEM where L is the leaving group and the W groups are the electron withdrawing groups.
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机译:一种氰基丙烯酸酯单体粘合剂配方,由于在配方中包含有效量的增强热固化性能的氰基丙烯酸酯单体粘合剂配方,其特征在于单,多或杂芳族化合物的特征在于在其芳环上至少被三个取代,从而提高了固化聚合物的耐热性,所述取代中的两个或更多个是吸电子基团,其选自NO 2,CN,CF 3,NR 1 3 +,SR 1 2 +,C(= O)R 1。 ,C(= O)OR 1,NO,CCl 3,SO 2,S(= O),SO 3,SO 2 R 1,SO 2 OR 1和F,一个或多个所述取代是选自以下组的基团:由F,Br,Cl,I,NO 2,CN,SOR 1,SO 2 R 1和SO 2 OR 1组成,并且R 1是任选取代的烃基。这种化合物的实例具有下式:其中L是离去基团,W是吸电子基团。
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