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Measuring process of at least one element chosen from Pu(IV), Pu(VI), uranium and nitrates present in a solution by liquid chromatography

机译:液相色谱法测定溶液中存在的至少一种选自Pu(IV),Pu(VI),铀和硝酸盐的元素的过程

摘要

Process for measuring the concentration of at least one element, selected from Plutonium (IV), Plutonium (VI), uranium and nitrates, present in a solution, by liquid chromatography, comprises: (a) injection of a sample of the solution onto a stationary phase comprising an aprotic support; (b) elution of the sample by a liquid mobile phase which comprises an ammonium type counter ion, a sulphate ion, an acid of at least 0.001 N, a mixture of solvents comprising a 1-4C alcohol, a polar organic solvent modifier different from the alcohol and miscible with water, and water to obtain an eluant; (c) analysis of the eluant to determine the elements in the sample; and (d) measuring these elements.
机译:通过液相色谱法测量溶液中存在的至少一种选自P(IV),P(VI),铀和硝酸盐的元素的浓度的方法包括:(a)将溶液样品注入到包含非质子载体的固定相; (b)通过包含铵型抗衡离子,硫酸根离子,至少0​​.001 N的酸,包含1-4C醇的溶剂混合物,与极性不同的极性有机溶剂改性剂的液体流动相洗脱样品与醇和水混溶,并用水洗提洗脱液; (c)分析洗脱液以确定样品中的元素; (d)测量这些元素。

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