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Cationic, advanced epoxy resin compositions incorporating glycidyl ethers of oxyalkylated aromatic or cycloaliphatic diols
Cationic, advanced epoxy resin compositions incorporating glycidyl ethers of oxyalkylated aromatic or cycloaliphatic diols
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机译:阳离子,高级环氧树脂组合物,其中掺入了烷氧基化的芳族或脂环族二醇的缩水甘油醚
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摘要
An advanced epoxy cationic resin useful as a cathodic electrodeposition coating is prepared by reacting in the presence of a suitable catalyst (A) a composition comprising (1) at least one diglycidyl ether of (a) an oxyalkylated aromatic diol or (b) an oxyalkylated cycloaliphatic diol or (c) certain oxyalkylated aliphatic diols and (2) at least one diglycidyl ether of a dihydric phenol with (B) at least one dihydric phenol and optionally (C) a monofunctional capping agent. Components (A-1) and (A-2) are employed in quantities such that from 10 to 75 weight percent of the diglycidyl ethers contained in component (A) are contributed by component (A-1), and from 25 to 90 weight percent of such glycidyl ethers are contributed by component (A-2). The terminal oxirane groups in the thus formed advanced epoxy resin are converted to cationic groups by reacting the resin with a nucleophilic compound and adding an organic acid and water at at least one point in the reaction.
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