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Chemorheologically tailored matrix resin formulations containing anhydride curing agents

机译:含酸酐固化剂的化学流变定制基质树脂配方

摘要

Chemorheologically viscosity tailored matrix resin formulations for use in forming prepregs and composite articles are disclosed. These formulations have a specified viscosity profile obtained from a curable matrix resin and an effective amount of a reactive resin curing agent reactive at room temperature and a latent resin curing agent substantially nonreactive at room temperature. The latent resin curing agent is activated upon heating or radiation. The matrix resin formulation is adapted upon formulation to have a viscosity sufficiently low enough to enable the matrix resin to impregnate fibers or broadgoods at room temperature without the necessity for the application of heat or solvent and which, upon standing at room temperature after impregnation into the fibers or broadgoods to form a prepreg composition, rises in viscosity. The matrix resin in the prepreg experiences a reduction in viscosity upon heating to a viscosity minimum sufficiently low to allow the matrix resin to flow and substantially eliminate formation of voids in the composite article from said prepreg yet not so low as to permit excessive bleeding of the matrix resin from the prepreg. With continued heating, the matrix resin in the composite article cures to a hardened or gelled state.
机译:公开了用于形成预浸料和复合制品的化学流变学粘度定制的基质树脂制剂。这些配方具有从可固化的基质树脂获得的特定粘度曲线,以及在室温下有效量的反应性树脂固化剂和在室温下基本上不反应的潜伏性树脂固化剂。潜在的树脂固化剂在加热或辐射时被活化。基质树脂制剂在配制时适合于具有足够低的粘度,以使基质树脂能够在室温下浸渍纤维或宽大物品,而无需施加热量或溶剂,并且在浸渍到室温下后在室温下静置。形成预浸料组合物的纤维或粗制品的粘度增加。预浸料中的基体树脂在加热到最低粘度时会降低粘度,该最低粘度应足够低,以使基体树脂能够流动并基本消除复合制品中所述预浸料中的空隙的形成,但不应低到足以使基料过度渗漏的程度。预浸料的基体树脂。随着连续加热,复合制品中的基质树脂固化成硬化或胶凝状态。

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