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Optical active chemical compound, liquid crystal material and liquid crystal indicating element

机译:光学活性化合物,液晶材料和液晶指示元件

摘要

NEW MATERIAL:An optically active compound having an cyano group and expressed by formula I [R1 is 1-18C optically active or inactive alkyl, alkoxy, alkoxycarbonyl, alkanoyloxy, alkoxyalkyl, alkoxyalkoxy, etc.; ring A is formula II to formula V (X is F, Cl or CN), etc.; R2 is 1-10C optically active or optically inactive alkyl; C* is asymmetric carbon atom having (R) or (S) configuration]. EXAMPLE:4-(4-Octyloxyphenyl)benzoic acid 4-[1-(R)-cyano-3-methylbutyloxy] phenyl. USE:Useful as a liquid crystal composition and material for liquid crystal display. The compound expressed by formula I is effective as a material and raw mate rial for ferroelectric liquid crystal display, especially having excellent response and memory property. PREPARATION:A compound expressed by formula VI is used as a starting raw material to afford an intermediate compound expressed by formula VII, which is then reacted with a compound expressed by formula VIII to provide the compound expressed by formula I.
机译:新材料:具有氰基并由式I表示的光学活性化合物[R 1为1-18C的光学活性或非活性烷基,烷氧基,烷氧基羰基,链烷酰氧基,烷氧基烷基,烷氧基烷氧基等。环A为式II至式V(X为F,Cl或CN)等。 R 2为1〜10C的光学活性或光学惰性的烷基。 C *是具有(R)或(S)构型的不对称碳原子]。实施例:4-(4-辛氧基苯基)苯甲酸4- [1-(R)-氰基-3-甲基丁氧基]苯基。用途:用作液晶显示的液晶组成和材料。由式I表示的化合物可有效地用作铁电液晶显示器的材料和原料,特别是具有优异的响应性和存储性能。制备:将式VI表示的化合物用作起始原料,以提供式VII表示的中间体化合物,然后将其与式VIII表示的化合物反应以提供式I表示的化合物。

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