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POLYMER CROSSLINKED WITH CROSSLINKER CONTAINING SACCHARIDE RESIDUE AND OPHTHALMIC LENS MADE OF THIS POLYMER AND PROCESS FOR THEIR PREPARATION

机译:含糖残渣交联剂的交联聚合物和该聚合物制成的眼科镜片及其制备方法

摘要

The polymers according to the invention consist of a hydrophilic artificial sea and a cross-functional compound of the general formula [S- (A) n] y containing a polylfunctional saccharide tube, in which S is a five- or six-membered saccharide ring, A is - (CH2) b - O - R2 - (R3) c - (R4) t - (CONH % 15 - R5), n is a number between 2 and 4, y is a number between 1 and 4, b is 0 or 1, provided that at least one A for b is 1, c is 0 or 1, R2 is - (CH2CHR6O) x, R6 is hydrogen or methyl, x is a number between 8 and 250, R3 is - CONH - R7 - NHOC -, R7 is a divalent tube which is or isopropyl diisocyanate or diisocyanate tube, R4 is X1 - [CH2 (CHR6) aX] zCH2 (CHR6) a-X when c = 1 and ű = 1 or R4 is - O - R8 if ű = 0 , t is 0 or 1, X is O or NH, X1 is O or NH, a is 0 to 3, z is 10 to 180, R8 is - (CHR6CH2O) f (CH2) e [C (R9) 2] dC (R9) 3, R 9 is a hydrogen or fluorine atom, d is a number from 0 to 30, e is a number from 1 to 69, f is a number from 0 to 60, R5 is a free radical reactive end port, and is 0 or 1, provided that the radical is is 1 for at least one A per y-tube. ŕ
机译:根据本发明的聚合物由亲水性人造海和含有多官能糖管的通式[S-(A)n] y的交叉官能化合物组成,其中S为五元或六元糖环,A是-(CH2)b-O-R2-(R3)c-(R4)t-(CONH <%15>-R5),n是2到4之间的数字,y是1到4之间的数字。 ,b为0或1,前提是b的至少一个A为1,c为0或1,R2为-(CH2CHR6O)x,R6为氢或甲基,x为8至250之间的数字,R3为- CONH-R7-NHOC-,R7为二价管,即为异丙基二异氰酸酯或二异氰酸酯管,R4为X1- [CH2(CHR6)aX] zCH2(CHR6)aX当c = 1且ű= 1或R4为-O时-R8如果if = 0,t为0或1,X为O或NH,X1为O或NH,a为0至3,z为10至180,R8为-(CHR6CH2O)f(CH2)e [C (R9)2] dC(R9)3,R 9为氢或氟原子,d为0至30的数,e为1至69的数,f为0至60的数,R5为a自由基反应末端ort为0或1,前提是每个y管中至少一个A的基团为1。 ŕ

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