首页> 外国专利> PRODUCTION OF CELLULOSE BY THE SODA-ANTHRAQUINONE PROCESS (SAP) WITH RECOVERY OF THE BOILING CHEMICALS

PRODUCTION OF CELLULOSE BY THE SODA-ANTHRAQUINONE PROCESS (SAP) WITH RECOVERY OF THE BOILING CHEMICALS

机译:苏打-蒽醌法(SAP)生产纤维素并回收沸腾化学物质

摘要

for the production of cellulose from wood and annual plants is a process of boiling in the boiling liquor contains a lye and sodium salts of appropriate alkylbenzu00e8nesulfoniques acids or carboxylic acids aromatic and aliphatic.by addition of anthraquinone or derivatives of this substance in the solution is boiled, the delignification. it is not necessary to limit the amount of hydroquinone is added, due to the price of the material, the fact that the anthraquinone resists wet oxidation and can be used in the process of boiling.the solubility and, therefore, the action of the anthraquinone is increased through the use of salts of the sulfonic acid.to get the chemicals present in the black liquor to boil, it is proposed that the lignin precipitate in the solution with a mineral acid or a carboxylic acid, as the case may be.separation of hemicelluloses by ultrafiltration and resin extraction and burning the remaining organic compounds and other salts of the sulfonic acid and salts of the carboxylic acid by oxidation in the aqueous phase with air or oxygen.the solution of chemicals released by the decomposition products of the wood can be reintroduced into the caustic liquor, carbonates, and disposal after partial crystallization of the aliphatic carboxylic acid salts, in the circuit of the pr production of cellulose.sodium acetate isolated by crystallization can be divided into acetic acid and sodium hydroxide by electrolysis using a diaphragm. the lye is reintroduced in the cooking process, the acetic acid is treated separately.
机译:用于从木材和一年生植物生产纤维素的方法是在沸腾的液体中沸腾的过程,其中包含碱液和适当的烷基苯磺酸盐或芳香族和脂肪族羧酸的钠盐,方法是在溶液中加入蒽醌或该物质的衍生物煮沸后,脱木素。由于材料的价格,不必限制对苯二酚的添加量,因为蒽醌抗湿氧化并且可以用于沸腾过程中,因此溶解度以及蒽醌的作用通过使用磺酸的盐增加木质素的含量以使黑液中存在的化学物质沸腾,建议视情况而定,木质素与无机酸或羧酸一起沉淀在溶液中。通过超滤和树脂萃取分离半纤维素,并在水相中与空气或氧气氧化,燃烧剩余的磺酸的有机化合物和其他盐以及羧酸的盐。木材分解产物释放出的化学溶液可以在纤维素的生产过程中,将其重新引入苛性液,碳酸盐中,并在部分结晶脂肪族羧酸盐后进行处理。通过结晶分离的乙酸钠可以通过使用隔膜的电解而分为乙酸和氢氧化钠。将碱液重新引入蒸煮过程中,将乙酸单独处理。

著录项

  • 公开/公告号EP0593743B1

    专利类型

  • 公开/公告日1998-01-14

    原文格式PDF

  • 申请/专利权人 GRANIT S.A.;

    申请/专利号EP19930911418

  • 申请日1993-04-30

  • 分类号D21C3/02;D21C3/22;D21C11/00;D21C11/14;

  • 国家 EP

  • 入库时间 2022-08-22 02:50:33

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