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Preparation process of supported catalysts including a centrifugation step of the support after impregnation

机译:负载型催化剂的制备方法,包括浸渍后载体的离心步骤

摘要

Process for the manufacture of supported catalysts including the stages: - (a) of preparation of a coating suspension containing at least one refractory inorganic oxide and at least some of the elements intended to form the catalytically active phase (A); - (b) of filling at least some of the open porosity of a support with this suspension; - (c) of draining the filled support by centrifuging; - (d) of heat treatment of the support to obtain a support coated with a porous layer; - (e) optionally of impregnation of the coated support with a solution containing the remainder of the element(s) of the catalytically active phase (A); and - (f) of thermal activation of the catalyst. This process of preparation is of particular interest in the manufacture of catalysts for the treatment of exhaust gases of internal combustion engines, in which the porous layer deposited on a support includes especially a refractory inorganic oxide, iron oxide and cerium oxide, and, by way of catalytically active element, at least one noble metal such as platinum, rhodium or palladium.
机译:制备负载型催化剂的方法包括以下步骤:-(a)制备包含至少一种难熔无机氧化物和至少一些旨在形成催化活性相(A)的元素的涂料悬浮液; -(b)用该悬浮液填充载体的至少一些开放孔隙率; -(c)通过离心方法排干填充的支撑物; -(d)对载体进行热处理以获得涂覆有多孔层的载体; -(e)任选地用包含催化活性相(A)的其余元素的溶液浸渍涂覆的载体; -(f)催化剂的热活化。在制备用于处理内燃机的废气的催化剂中,该制备方法特别有意义,其中沉积在载体上的多孔层尤其包括难熔的无机氧化物,氧化铁和氧化铈,并且通过至少一种贵金属如铂,铑或钯。

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