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METHOD OF QUANTIFYING PERFORMANCE CHEMICALS IN PULP AND PAPER

机译:纸浆和造纸中性能化学品的定量方法

摘要

A method for quantifying of the amounts of reacted and/or retained performance chemicals selected from the group consisting of wet strength agents, starches and retention agents, hydrophobic agents and debonding agents in pulp and/or paper, which method comprises (I) developing a calibration model by (I.a) registering absorption, reflectance or emission spectra of reference samples of papers containing known amounts of the said reacted and/or retained performance chemicals to develop learning sets; (I.b) processing the spectral raw data, to reduce noise and adjust for drift and diffuse light scatter; (I.c) performing a data analysis by applying chemometric techniques to the processed learning sets; and (II) determining the unknown amounts of reacted and/or retained pulp and paper performance chemicals selected from the group consisting of wet strength agents, starches and retention agents, hydrophobic agents and debonding agents by registering the absorption, reflectance or emission spectrum, in correspondence to (I.a), from the pulp and/or paper of the unknown amounts of the said reacted and/or retained performance chemicals of pulp and paper; processing the thereby obtained spectral raw data as according to (I.b); and applying the developed calibration model to the processed data. Optionally, a data analysis step as according to (I.c) can also be applied to the processed spectral raw data from the paper of the unknown amounts of the said reacted and/or retained performance chemicals.
机译:一种定量反应的和/或保留的性能化学品的量的方法,所述化学和化学性能选自纸浆和/或纸中的湿强度剂,淀粉和保留剂,疏水剂和脱胶剂,该方法包括(I)显影通过(Ia)记录包含已知量的所述反应和/或保留的性能化学品的纸张的参考样品的吸收,反射或发射光谱的校准模型以建立学习集; (I.b)处理光谱原始数据,以减少噪声并调整漂移和漫射光散射; (I.c)通过将化学计量学技术应用于处理后的学习集来执行数据分析; (II)通过记录吸收,反射或发射光谱,确定未知量的反应和/或保留的纸浆和造纸性能化学品,其选自湿强剂,淀粉和固着剂,疏水剂和脱胶剂。纸浆和/或纸中未知量的所述纸浆和纸的已反应和/或保留的性能化学品与(Ia)的对应关系;根据(I.b)处理由此获得的光谱原始数据;并将开发的校准模型应用于处理后的数据。任选地,还可以将根据(I.c)的数据分析步骤应用于来自纸的未知量的所述反应的和/或保留的性能化学品的经处理的光谱原始数据。

著录项

  • 公开/公告号EP0760094B1

    专利类型

  • 公开/公告日1998-04-22

    原文格式PDF

  • 申请/专利权人 EKA CHEMICALS AB;

    申请/专利号EP19950920336

  • 发明设计人 OLSSON RALF;RENBERG LARS;HELMER ULLA;

    申请日1995-05-12

  • 分类号G01N21/84;G01N33/34;

  • 国家 EP

  • 入库时间 2022-08-22 02:50:09

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