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The balanced decarboxylation of aromatic polycarboxylic acids - a one-step synthesis of perylene-3,4-dicarboxylic acid anhydride

机译:芳香族多元羧酸的平衡脱羧-,-3,4-二羧酸酐的一步合成

摘要

Preparation of perylene-3,4-dicarboxylic anhydrides of formula (I) in which R1, R2, R3, R4, R5, R6, R7, R8 are hydrogen, or one radical to eight radicals are a radical selected from the group consisting of an unsubstituted or substituted carbocyclic aromatic radical, an unsubstituted or substituted heterocyclic aromatic radical, halogen, unsubstituted or substituted C1-C18alkyl, -OR9, CN, -NR10R11, -COR12, -NR13COR12, -NR9COOR12, -NR9CONR10R11, -NHSO2R12, -SO2R12, -SOR12, -SO2OR12, -CONR10R11, -SO2NR10R11, -N=NR14, -OCOR12 and -OCONHR12, where each two adjacent radicals together can form a carbocyclic or heterocyclic ring; where R12 is C1-C18alkyl, C6-C10aryl or benzyl which is unsubstituted or substituted by halogen, C1-C4alkyl or C1-C4alkoxy or is a five- to seven-membered heterocyclic radical, R10 and R11 independently of one another are hydrogen, C1-C18alkyl, C3-C24cycloalkyl, C6-C10-aryl, each of which is unsubstituted or substituted by cyano or hydroxyl groups or 5- to 7-membered heteroaryl, or in which R10 and R11 together with at least one of the other radicals R1 to R8 form a 5- or 6-membered carbocyclic or heterocyclic ring; R9 is hydrogen, C1-C18alkyl, C3-C24cycloalkyl, C6-C10aryl or 5- to 7-membered heteroaryl, R13 is hydrogen, C1-C18alkyl, C3-C24cycloalkyl, C1-C4alkylaryl, each of which is unsubstituted or substituted by cyano, hydroxyl or C1-C4alkoxycarbonyl groups, C6-C10aryl which is unsubstituted or substituted by halogen, C1-C4alkyl or C1-C4alkoxy groups, or is a 5- to 7-membered heterocycle, and R14 is the radical of a coupling component or C6-C10aryl which is unsubstituted or substituted by halogen, C1-C4alkyl or C1-C4alkoxy groups by reacting perylene-3,4:9,10-tetracarboxylic anhydride of formula (II) in which R1 to R8 are defined as indicated above, with a sterically hindered amine as a base at elevated temperature, processes for the preparation of further perylene derivatives, perylene derivatives and their use.
机译:式(I)的per-3,4-二羧酸酐的制备,其中R 1,R 2,R 3,R 4,R 5,R 6,R 7 >,R 8为氢,或一个基团至八个基团为选自未取代或取代的碳环芳族基团,未取代或取代的杂环芳族基团,卤素,未取代或取代的C 1 -C 18烷基的基团,- OR <9>,CN,-NR <10> R <11>,-COR <12>,-NR <13> COR <12>,-NR <9> COOR <12>,-NR <9> CONR < 10> R <11>,-NHSO2R <12>,-SO2R <12>,-SOR <12>,-SO2OR <12>,-CONR <10> R <11>,-SO2NR <10> R <11> ,-N = NR 14,-OCOR <12>和-OCONHR <12>,其中每个相邻的两个基团一起可以形成碳环或杂环。其中R 12为未被取代或被卤素取代的C 1 -C 18烷基,C 6 -C 10芳基或苄基,C 1 -C 4烷基或C 1 -C 4烷氧基或为五至七元杂环基,R 10和R 11彼此独立的是氢,C 1 -C 18烷基,C 3 -C 24环烷基,C 6 -C 10芳基,它们各自未被取代或被氰基或羟基或5至7元杂芳基取代,或其中R 10 R 11与至少一个其他基团R 1至R 8一起形成5或6元碳环或杂环。 R 9为氢,C 1 -C 18烷基,C 3 -C 24环烷基,C 6 -C 10芳基或5至7元杂芳基,R 13为氢,C 1 -C 18烷基,C 3 -C 24环烷基,C 1 -C 4烷基芳基,各自为R 14是未被取代或被氰基,羟基或C 1 -C 4烷氧基羰基取代的,未被取代或被卤素,C 1 -C 4烷基或C 1 -C 4烷氧基或5至7元杂环的C 6 -C 10芳基,且R 14为通过使式(II)的per-3,4:9,10-四羧酸酐反应,使未被取代或被卤素,C1-C4烷基或C1-C4烷氧基取代的偶联组分或C6-C10芳基的基团,其中R <1如上所定义,R 1至R 8以在高温下以位阻胺为碱,另外的per衍生物的制备方法,per衍生物及其用途。

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