首页> 外国专利> CATALYTICAL PROCEDURE FOR THE IMPLEMENTATION OF COAL WATER STRUCTURES, INCLUDING NETHERLANDS ALKANS, INTO ESTER, ALCOHOLE AND, IF NECESSARY, COAL WATER MATERIALS

CATALYTICAL PROCEDURE FOR THE IMPLEMENTATION OF COAL WATER STRUCTURES, INCLUDING NETHERLANDS ALKANS, INTO ESTER, ALCOHOLE AND, IF NECESSARY, COAL WATER MATERIALS

机译:实施煤水结构的催化方法,包括荷兰的阿尔坎斯,酯,醇以及必要时的煤水材料

摘要

This invention is a process for converting lower alkanes into their corresponding esters and optionally into various intermediates (such as alcohols) and other liquid hydrocarbons. The alkanes are oxidatively converted to oxy-esters at high selectivity and conversion and at practical reaction rates using at least catalytic amounts of certain class "B" metals and/or metal ions defined by the Pearson definition as "soft" or "borderline". Desirable catalysts comprise such metals as Pd, Tl, Pt, Hg, and Au. If so desired, the alkyl oxy-esters may be converted to alcohols or other intermediates such as alkyl halides. The oxy-esters, alcohols, and other intermediates may optionally be converted to liquid hydrocarbons such as gasoline.
机译:本发明是一种将低级烷烃转化成它们相应的酯,并任选地转化成各种中间体(如醇)和其他液态烃的方法。使用至少催化量的某些皮尔逊定义为“软”或“边界线”的某些“ B”类金属和/或金属离子,以高选择性和转化率以及以实际反应速率将烷烃氧化转化为氧基酯。理想的催化剂包括诸如Pd,Tl,Pt,Hg和Au的金属。如果需要的话,可以将烷氧基酯转化为醇或其他中间体,例如卤代烷。含氧酯,醇和其他中间体可以任选地转化为液态烃,例如汽油。

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