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PROCESS FOR THE SELECTIVE SEPARATION OF ACTINIDES (III) AND LANTHANIDES (III)

机译:素(III)和镧系元素(III)的选择性分离过程

摘要

The subject of the present invention is a process for the selective separation of actinides (III) and lanthanides (III) from a reaction medium containing them, more precisely the present invention allows a selective extraction of actinides (III) by using a reaction medium. aqueous solution containing pertechnetate ions TcO4 ** -. The preferred extraction agents are chosen from picolinamides and their derivatives. This process finds particular application in the separation of actinides (III) from high activity raffinates generated during the reprocessing of nuclear fuels according to the method of the present invention. solvent extraction known as the "PUREX" process.
机译:本发明的主题是从包含them系元素(III)和镧系元素(III)的反应介质中选择性分离separation系元素(III)的方法,更准确地说,本发明允许通过使用反应介质选择性地提取act系元素(III)。含高tech酸根离子TcO4 **的水溶液。优选的提取剂选自吡啶甲酰胺及其衍生物。该方法在从根据本发明的方法的核燃料的后处理过程中产生的高活性提余液中分离act系元素(III)中发现了特殊的应用。溶剂萃取称为“ PUREX”工艺。

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