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Selective ring-opening way of naphthenic ring

机译:环烷环的选择性开环方式

摘要

(57) and containing at least one 5 ring C having at least one substituent, further, cyclic compounds, some to 5 ring C having the substituent at least present in [Abstract] The feed stream is at least 8 carbon atoms, the average number of carbon atoms, the selective opening of the naphthene ring method of naphthenic ring-containing compound in the feed stream.5 naphthene ring this C is opened without dealkylation significantly pendant all substituents of the ring. It is contacted with a catalyst comprising a metal selected effective amount of the the catalyst carrier on, and mixtures thereof, as well as Rh Ir, and Ru, further, the hydrocarbon feed stream containing such compounds, the When it is reacted with the feed consisting of 20 wt% in heptane diluent from n- pentyl-cyclopentane, catalyst, to C 10 paraffinic product of at least 0.80 and C 10 paraffins RuiOsamu-ritsu at least 25% selectivity (However, selectivity is defined by the C 10 ring disappearance% C 10 paraffin RuiOsamu-ritsu /%) would be.
机译:(57)并包含至少一个具有至少一个取代基的 5 环C,以及环状化合物,某些环状化合物至少在[Sub> 5 环C中具有至少一个取代基。 ]进料流中至少有8个碳原子,平均碳原子数,进料流中含环烷烃化合物的环烷环法的选择性开环。 5 环烷环,此C为没有脱烷基的开环显着地悬垂了环的所有取代基。将其与包含金属的催化剂接触,该催化剂包含金属的选定有效量的催化剂载体及其混合物,以及Rh Ir和Ru,还包括含有此类化合物的烃类进料流,当与进料反应时,由正戊基环戊烷,催化剂的庚烷稀释剂中的20 wt%组成的至少<0.8>的C 10 链烷烃产物和至少25的C 10 链烷烃RuiOsamu-ritsu选择性%(但是,选择性是由C 10 环消失%C 10 石蜡RuiOsamu-ritsu /%定义)。

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