Production manner of 2 (displacement benzoyl) 1,3 cyclohexane dione

摘要

(57) Abstract The chemical compound formula (i) [in formula, R¹, R², R³, R⁴, R⁵ and R⁶ becoming independent, hydrogen or is C_1-6 alkyls; R⁷ halogen, cyano and NO₂, (R _{a they} are C_1-4 alkyls,) is C_1-4 alkyls, C_1-4 halo alkyls, C_1-4 alkoxy or R _aS; R⁸, as for R⁹ and R¹⁰ becoming independent, hydrogen and halogen, C_1-4 alkyls, C_1-4 alkoxy and C_1-4 halo alkyls, C_1-4 haloalkoxies, CN and NO₂, the phenoxy or the displacement phenoxy, R _bS (O) _{nO m} (as for m 0 or 1 is, as for n 0, 1 or 2 it is, as for R _{b it} is C_1-4 alkyls, C_1-4 halo alkyls, phenyl or the benzyl,), NHCOR _c (as for R _{c they} are C_1-4 alkyls,), NR _{dR e} (R_d and as for R _e becoming independent, hydrogen or C_1-4 alkyls is), R _fC (O) - (R _f hydrogen, is C_1-4 alkyls, C_1-4 halo alkyls or C_1-4 alkoxy,), (as for R _g and R _h becoming independent, hydrogen or they are C_1-4 alkyls,) it is SO₂ NR _{gR h,} or or R⁸, R the inside either⁹ and R¹⁰ as for two the carbon atom which those have joined and together, maximum of 3 various atoms which are chosen from O, N or SSomething which forms the complex ring of 5 or 6 members who are included, as for these it is possible to be displacement] being production manner with =NOC1 _{- 4} alkyls, C_1-4 alkyls, C_1-4 halo alkyls, C_1-4 alkoxy or halogen with desire, the chemical compound formula (ii) [in formula, R¹, R², R³, R⁴, R⁵, R⁶, R⁷, R⁸, as for R⁹ and R^{10 it} decides aforementioned in regard to formula (i) it is,] in the nonpolar solvent cyanide chemical material source, alkaline or alkaline earths metal carbonic acidThe manner which includes the fact that it makes transpose under existing of the water of 1 - 6 mols vis-a-vis the portable catalytic converter between the salt and phase, and the chemical compound formula (ii).