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Itaconate copolymer having a second-order nonlinear optical properties

机译:具有二阶非线性光学性质的衣康酸酯共聚物

摘要

PROBLEM TO BE SOLVED: To provide a high molecular compound having a nonlinear optical characteristic, together with a high nonlinear optical constant and thermal stability by specifying the constitution of a side chain type quadratic nonlinear itaconate copolymer. ;SOLUTION: A quadratic nonlinear itaconate copolymer of side chain type shown by the formula I is used, where the ITCN-NLO unit is a substitution itaconate unit shown by the formula II, the MO unit is such a unit as capable of forming a copolymer with the ITCN-NLO unit, and (m) and (n) stand for the numerals where (m+n) is between 5 and 10,000, and m/(m+n) between 0.05 and 0.95. In the formula II, X shows an alkylene group having a single bond and carbons between 1 and 12, or a bivalent aromatic hydrocarbon group having carbons between 6 and 12, and Y shows a bivalent bond selected from a group of an ether bond, an ester bond, an amide bond, an alkyl imino bond having carbons between 1 and 5, a sulfon bond or the like. Also, NLO shows a quadratic nonlinear optically activated group as a conjugate aromatic group not substituted or substituted by an electron donating group and/or an electron attractive group.;COPYRIGHT: (C)1998,JPO
机译:解决的问题:通过指定侧链型二次非线性衣康酸酯共聚物的结构,提供具有非线性光学特性以及高非线性光学常数和热稳定性的高分子化合物。 ;解决方案:使用式I所示的二次侧链型非线性衣康酸酯共聚物,其中ITCN-NLO单元为式II所示的取代衣康酸酯单元,MO单元为能够形成共聚物的单元(m)和(n)代表数字,其中(m + n)在5到10,000之间,而m /(m + n)在0.05到0.95之间。在式II中,X表示具有单键且碳数在1至12之间的亚烷基或具有碳数在6至12之间的二价芳族烃基,并且Y表示选自醚键的基团中的二价键。酯键,酰胺键,碳数在1至5之间的烷基亚氨基键,磺键等。而且,NLO显示出二次非线性光学活化基团,其为未被给电子基团和/或吸电子基团取代或取代的共轭芳族基团。;版权:(C)1998,JPO

著录项

  • 公开/公告号JP2937972B2

    专利类型

  • 公开/公告日1999-08-23

    原文格式PDF

  • 申请/专利权人 KANKOKU KAGAKU GIJUTSU KENKYUSHO;

    申请/专利号JP19970315037

  • 发明设计人 SO SOYOPU;KIN RAKUCHU;SAI TOKUN;

    申请日1997-11-17

  • 分类号G02F1/35;C08F220/14;G02F220/32;G02F222/10;G02F222/20;G02F222/24;G02F222/36;G02F222/40;C09K3/00;C09K9/02;

  • 国家 JP

  • 入库时间 2022-08-22 02:31:47

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