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Compositions of the additives in synthetic latex emulsions of epoxy silane in dispersions of reactive polymer base water and process for preparing

机译:反应性聚合物基础水分散体中环氧硅烷合成胶乳乳液中添加剂的组成和制备方法

摘要

The present invention provides stable epoxy silane emulsions and methods for the preparation of a stable epoxy-silane emulsions comprising: (I) a water insoluble or slightly soluble epoxysilane; (II) an emulsifier; (III) water; and (IV) a water dispersible polymer containing a functional group with an active hydrogen. Also provided are two part systems such that an epoxysilane emulsion comprising components (I)-(III) are combined and the component (IV) may be added upon use of components (I) to (III). Moreover, additional components (V), such as catalysts and pH buffers may be added. Said compositions may be used for, among other things, coatings, adhesives and sealants. The water dispersible or slightly soluble epoxy functional silane for use herein are of the general structure R1aR2bSi(OR3)4-a-b where R1 is an epoxy substituted alkyl or aralkyl group, where the alkyl may have from four to thirty carbon atoms, R3 is an alkyl or alkoxy-substituted alkyl, aryl or aralkyl group having from two to ten carbon atoms, R2 is an alkyl group or alkoxy substituted alkyl, aryl or aralkyl group having from one to ten carbon atoms, a is one to three, and b is zero to two, with the proviso that a+b is 1, 2, or 3. R1, R2, and R3 group may be cyclic, branched or linear.
机译:本发明提供了稳定的环氧硅烷乳液和制备稳定的环氧硅烷乳液的方法,包括:(I)水不溶性或微溶性环氧硅烷; (II)乳化剂; (三)水; (IV)包含具有活性氢的官能团的水分散性聚合物。还提供了两部分体系,使得包含组分(I)-(III)的环氧硅烷乳液被合并,并且可以在使用组分(I)至(III)时添加组分(IV)。而且,可以添加另外的组分(V),例如催化剂和pH缓冲剂。所述组合物尤其可以用于涂料,粘合剂和密封剂。本文所用的水分散性或微溶性环氧官能硅烷具有通用结构R1aR2bSi(OR3)4-ab,其中R1为环氧取代的烷基或芳烷基,其中烷基可具有4至30个碳原子,R3为具有2至10个碳原子的烷基或烷氧基取代的烷基,芳基或芳烷基,R 2为烷基或具有1至10个碳原子的烷氧基取代的烷基,芳基或芳烷基,a为1-3,b为从0到2,但a + b为1、2或3。R1,R2和R3基团可以是环状,支链或线性的。

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