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red synthetic mica and those containing abschirmendes resources against ultraviolet radiation

机译:红色合成云母和含有abschirmendes资源的合成云母可抵抗紫外线辐射

摘要

The object of the present invention is to provide composite synthetic mica powder having excellent ultraviolet ray screening effect. The composite synthetic mica powder of the present invention is characterized in that a mica fine particle layer (B) containing one or more types of elements selected from a group of Te, Bi, Pb, Ce, Fe, Mo, Nb, W, Sb, Sn, V, Mn, Ni, Co, Zn and Ti is formed on the surface of scale-like mica particles (A), whereby: covering ratio of said particles (A) by said particles (B) is lower than or equal to 1 and higher than or equal to 0.5; and ratio of particle size of said particles (B) to plane direction diameter of said particles (A) is lower than or equal to 0.1, and particle size of said particles (A) is 1 to 100 mu m. Another object of the present invention is to provide red synthetic mica, which develops light-resistant red color closer to color of human skin and ultraviolet ray, and also to provide a method for manufacturing the same and an ultraviolet ray screening agent containing said synthetic mica. The synthetic mica of the present invention is characterized in that, it is expressed by the following formula (I): X1/3 SIMILAR 1 Y2 SIMILAR 3 (Z4 O10) F2x0.75 SIMILAR 2x0.99 (I (where X represents one or more types of ions selected from a group of Na, K, Li, Ca, Rb and Sr, Y represents one or more types of ions selected from a group of Mg, Fe, Ni, Mn, Al, Li, Co, Ti and Zn, Z represents one or more types of ions selected from a group of Al, Si, Ge, Fe, B, Co and Ti, and at least one of Y and Z represents an iron ion), molar number of iron contained in said synthetic mica is 0.01 to 3 mols, and, when said synthetic mica is measured by powder cell method, its color is given by L*=55 to 75, a*=5 to 20, and b*=5 to 20 by the CIE 1976 (L*a*b*) space. IMAGE
机译:本发明的目的是提供具有优异的紫外线屏蔽效果的复合合成云母粉。本发明的复合合成云母粉的特征在于,云母微粒层(B)含有选自Te,Bi,Pb,Ce,Fe,Mo,Nb,W,Sb中的一种以上的元素。在鳞片状云母颗粒(A)的表面上形成Sn,V,Mn,Ni,Co,Zn和Ti,从而:所述颗粒(B)对所述颗粒(A)的覆盖率小于或等于。等于1并大于或等于0.5;所述粒子(B)的粒径相对于所述粒子(A)的面径的比为0.1以下,所述粒子(A)的粒径为1〜100μm。本发明的另一个目的是提供红色的合成云母,其产生更接近人皮肤和紫外线颜色的耐光红色,并提供其制备方法和含有所述合成云母的紫外线屏蔽剂。 。本发明的合成云母的特征在于,其由下式(I)表示:X1 / 3〜1 Y2〜3(Z4O10)F2×0.75〜2×0.99(I>(X为1选自Na,K,Li,Ca,Rb和Sr的一种或多种离子,Y表示选自Mg,Fe,Ni,Mn,Al,Li,Co,Ti的一种或多种离子Zn,Z表示选自Al,Si,Ge,Fe,B,Co和Ti的组中的一种以上的离子,Y和Z中的至少一种表示铁离子。所述合成云母为0.01至3摩尔,并且当通过粉末电池法测量所述合成云母时,其颜色由L * = 55至75,a * = 5至20和b * = 5至20给出。 CIE 1976(L * a * b *)空间。

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