首页> 外国专利> A process for producing one or more caprolactamas replaced or insustituidas Epsilon,A process for producing one or more dealdehidos acid Salts and / or one or more precursors of Epsilon caprolactam, replaced or insustituidos,A reaction mixture generated in batches or in continu

A process for producing one or more caprolactamas replaced or insustituidas Epsilon,A process for producing one or more dealdehidos acid Salts and / or one or more precursors of Epsilon caprolactam, replaced or insustituidos,A reaction mixture generated in batches or in continu

机译:一种生产一种或多种己内酰胺替代品或工业化的Epsilon的方法,一种生产一种或多种Epsilon己内酰胺,替代品或工业品中的一种或多种脱脱亚氨基酸盐和/或一种或多种前体的方法,分批或连续产生的反应混合物

摘要

Processes for producing one or more caprolactamas replaced or insustituidas Epsilon caprolactam, for example a u00e9psilo,Comprising: (a) someteruno or more alcadienos replaced or insustituidos to hidroxicarbonilacion in presence of uncatalizador hidroxicarbonilacion,For example a catalystfor metal ligand Complex organofosforo,And Neutralization with a base to produce one or more acid salts pentenoico replaced or insustituu00eddas; b) one or more you make such pentenoico replaced or insustituidas to hidrofo acidRmilacion in the presence of a catalyst hidroformilacion, e.g. a metal ligand Complex Catalyst organofosforo,To produce one or more formilvalu00e9rico insustituidasy acid salts or replaced and / or one or more precursors of Epsilon carpolactama replaced or insustituidos; and (c) subjecting one or more of these saltsFormilvalu00e9rico replaced oinsustituidas acid and / or one or more precursors of Epsilon caprolactam replaced or insustituidos to Reductive amination in the presence of a Catalyst deaminacion ReducerAnd cyclization, optionally in the presence of a catalyst for cyclization.To produce these one or more u00e9psiloncarpolactamas replaced or insustituidas and reaction mixtures containing one or more substituted or insustituidas as Epsilon caprolactamas or productsMain reaction.
机译:生产一种或多种取代的己内酰胺或使之εε己内酰胺工业化的方法,例如,包括:(a)在无催化的锡碳昔甲腈存在下,将某一种或多种alcadienos取代或将其工业化成hidroxicarbonilacion,例如用于金属配位体配合物的金属化和金属配合物的催化剂用碱产生一种或多种戊烯酸取代或取代的戊二酸; b)在催化剂甲甲醛的存在下,使一种或多种此类戊烯酮取代或工业化为氟乙酸。金属配体络合物催化剂有机磷,用以生产一种或多种甲磺酸盐或被取代的和/或一种或多种Epsilon carpolactama的前体被取代或被取代; (c)在催化剂脱氨还原剂和环化的存在下,任选在催化剂的存在下,使一种或多种这些盐形成甲酰胺基取代的奥尼司地酸和/或一种或多种ε-己内酰胺取代的或前体的前体进行还原胺化。为产生这些一种或多种取代的或工业化的,含有一种或多种取代的或工业化的反应混合物,作为Epsilon己内酰胺或产物的主要反应。

著录项

  • 公开/公告号AR012407A1

    专利类型

  • 公开/公告日2000-10-18

    原文格式PDF

  • 申请/专利号AR1998P101688

  • 发明设计人

    申请日1998-04-14

  • 分类号C07D223/10;B01J38/48;

  • 国家 AR

  • 入库时间 2022-08-22 01:57:31

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