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The polymer modification in asphalt concrete.

机译:沥青混凝土中的聚合物改性。

摘要

"Polu00ecmero for modification in asphalt concrete.This invention describes a procedure for the synthesis of a polymer of styrene - butadiene, which is particularly useful for modification of asphalt to improve the ductility forced.The elastic recovery, the rigidity and toughness, by a process comprising the steps of: (1) continuous feeding of monomer 1,3-butadiene, an organo lithium compound.A polar modifier and an organic solvent to a first polymerization zone (2) to let the monomer of 1.3 - butadiene polymerizes in the said first polymerization zone to a conversion of at least about 90 percent, to produce a polymer solution live.It is understood that the said organic solvent and the chains of polybutadiene having a molecular weight of live, numerical medium which is within the range of about 20000 to about 60.000, (3) a continuous withdrawal of said polymer solution of said first reaction zone live, (4) the continuous feeding of monomer of styrene,Divinyl benzene and the solution of polymer alive and withdrawal of the first polymerization zone to a second polymerization zone (5) allow for the polymerization of styrene monomer and the monomerOf divinyl benzene in the second zone of polymerization, to produce a polymer solution of styrene - butadiene.Having a molecular weight of numerical medium that is within the range of about 30000 to about 85.000 and (6) to remove the solution continuously from said polymer of styrene butadiene polymerization of the second zone.
机译:本发明描述了一种苯乙烯-丁二烯聚合物的合成方法,该方法对改性沥青以改善强制延展性特别有用。其弹性回复率,刚性和韧性,通过包括以下步骤的方法:(1)将单体1,3-丁二烯,有机锂化合物,极性改性剂和有机溶剂连续进料到第一聚合区(2),以使1.3-丁二烯的单体聚合。在所述第一聚合区域中,至少约90%的转化率产生活性的聚合物溶液。可以理解的是,所述有机溶剂和聚丁二烯链的活性数字介质的分子量在该范围内。约20000至约60000,(3)所述第一反应区的所述聚合物溶液的连续排出带电,(4)苯乙烯,二乙烯基苯的单体和溶液的连续进料聚合物的活性化和将第一聚合区撤出到第二聚合区(5)允许苯乙烯单体和二乙烯基苯单体在第二聚合区内聚合,以生产苯乙烯-丁二烯的聚合物溶液。 (6)从第二区域的所述苯乙烯丁二烯聚合的聚合物中连续除去溶液。

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