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Process of preparing nanocomposites with activated interfaces prepared by mechanical milling of magnesium hydrides, and their use for hydrogen storage

机译:通过氢化镁的机械研磨制备的具有活化界面的纳米复合材料的制备方法及其在储氢中的用途

摘要

B "NANOCOMPOST PREPARATION PROCESS WITH ACTIVATED INTERFACES PREPARED BY MECHANICAL GRINDING OF MAGNESIUM HYDROTES, AND USE OF THE SAME FOR HYDROGEN STORAGE" D The present invention relates to new nanocomposites having activated magnesium based or magnesium based interfaces. of a compound containing magnesium and another chemical element or compound known to be capable of absorbing hydrogen and to be poorly miscible with magnesium or its hydride, such as, for example, vanadium, titanium or niobium. The method is characterized by the sunmission of magnesium or a magnesium-based compound known to absorb hydrogen, to a hydrogenation, in order to obtain the corresponding hydride in the form of a powder. Said result in a hydride powder with another element or compound or with a hydride of said other element or compound which and the result of the mixture is subjected to intensive mechanical grinding in order to obtain the corresponding nanocomposite in the form of a hydride. Finally, if necessary, the nanocomposite result is subjected to hydrogen desorption. The invention is also related to the result of the Mg-based nanocomposite. which has the advantage of being expansive and highly sufficient for hydrogen storage, obtaining its microstructure (which has the nature of its interfaces and the spatial distribution of its constituents) in which it is extremely thin and provides an excellent synergistic effect between Mg and the other element or compound.
机译:本发明涉及具有活化的基于镁或基于镁的界面的新型纳米复合材料,其具有通过镁水合物的机械研磨制备的具有活性界面的纳米复合材料制备方法,以及该方法在储氢中的用途。含有镁和另一种化学元素的化合物或已知能吸收氢并与镁或其氢化物互溶性差的化合物,例如钒,钛或铌。该方法的特征在于将镁或已知吸收氢的镁基化合物日光照射以氢化,以获得粉末形式的相应氢化物。所述结果导致与另一种元素或化合物的氢化物粉末或与所述另一种元素或化合物的氢化物,并对混合物的结果进行强烈的机械研磨,以获得氢化物形式的相应纳米复合材料。最后,如果需要,对纳米复合材料进行氢脱附。本发明还涉及基于Mg的纳米复合材料的结果。它具有膨胀性和足够用于储氢的优点,获得了极薄的微结构(具有其界面的性质和其组成的空间分布),并且在镁与其他镁之间具有出色的协同作用元素或化合物。

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