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WATERLESS SELF-EMULSIFIABLE BIODEGRADABLE CHEMICAL SOFTENING COMPOSITION USEFUL IN FIBROUS CELLULOSIC MATERIALS

机译:在纤维状纤维素材料中有用的水溶性自乳化生物可降解化学软化组合物

摘要

Substantially waterless self-emulsifiable biodegradable chemical softening compositions are provided comprising a mixture of an ester-functional quaternary ammonium compound and a polyhydroxy compound. Preferred biodegradable ester-functional quaternary ammonium compounds include diesterdialkyl dimethyl ammonium salts such as diester ditallow dimethyl ammonium chloride, diester di(touch hydrogenated)tallow dimethyl ammonium chloride and diester di(hydrogenated)tallow dimethyl ammonium chloride. Preferred polyhydroxy compounds are selected from the group consisting of glycerol, polyglycerols having a weight average molecular weight from about 150 to about 800 and polyoxyethylene glycols and polyoxypropylene glycols having a weight average molecular weight from about 200 to about 4000. The substantially waterless self-emulsifiable biodegradable chemical softening compositions are prepared by mixing the ester-functional quaternary ammonium compound with the polyhydroxy compound at a specific temperature range wherein the polyhydroxy compound is miscible with the ester-functional quaternary ammonium compound. The resulting stable solid or concentrated fluid mixture can then be economically shipped to the consumer or ultimate user. The ultimate users of the chemical softening composition simply dilute the mixture with a liquid carrier (e.g., water) to form an aqueous dispersion suitable for treating fibrous cellulosic material. The substantially waterless self-emulsifiable biodegradable chemical softening compositions disclosed herein are primarily intended for softening disposable paper products such as tissues and towels.
机译:提供了基本上无水的可自乳化的可生物降解的化学软化组合物,其包含酯官能的季铵化合物和多羟基化合物的混合物。优选的可生物降解的酯官能的季铵化合物包括二酯二烷基二甲基铵盐,例如二酯二牛脂二甲基氯化铵,二酯二(接触氢化)牛脂二甲基氯化铵和二酯二(氢化)牛脂二甲基氯化铵。优选的多羟基化合物选自甘油,重均分子量为约150至约800的聚甘油和重均分子量为约200至约4000的聚氧乙二醇和聚氧丙二醇。基本上无水的自乳化剂可生物降解的化学软化组合物是通过在特定温度范围内将酯官能的季铵化合物与多羟基化合物混合而制备的,其中多羟基化合物可与酯官能的季铵化合物混溶。然后可以将所得的稳定的固体或浓缩的流体混合物经济地运送到消费者或最终用户。化学软化组合物的最终使用者仅用液体载体(例如水)稀释混合物即可形成适用于处理纤维素纤维材料的水分散体。本文公开的基本上无水的可自乳化的可生物降解的化学软化组合物主要用于软化一次性纸制品,例如薄纸和毛巾。

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