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Catalyst based on modified NU-87 zeolite and a process for improving the pour point of feeds containing paraffins

机译:基于改性NU-87沸石的催化剂和提高含石蜡物料倾点的方法

摘要

The invention concerns a process for improving the pour point of a feed comprising paraffins containing more than 10 carbon atoms, in which process the feed to be treated is brought into contact with a catalyst comprising an NU-87 zeolite comprising silicon and at least one clement T selected from the group formed by Al, Fe, Ga and B, from which at least a portion of clement T has been removed, and having a global Si/T ratio of over 20, the catalyst also containing at least one hydro- dehydrogenating element. The process is carried out at a temperature which is in the range 170° C. to 500° C., a pressure in the range 1 to 250 bar and at an hourly space velocity in the range 0.05 to 100 h. sup.-1, in the presence of hydrogen in a proportion of 50 to 2000 l/l of feed. The oils obtained have good pour points and high viscosity indices (VI). The process is also applicable to gas oils and other feeds requiring a reduction of pour point. The catalyst is also claimed.
机译:本发明涉及一种用于改善包含含超过10个碳原子的链烷烃的进料的倾点的方法,在该方法中,使待处理的进料与包含NU-87沸石的催化剂接触,所述NU-87沸石包含硅和至少一种元素。 T选自Al,Fe,Ga和B形成的组中的T,其中至少一部分元素T已被除去,并且Si / T的整体比超过20,该催化剂还包含至少一种加氢脱氢元件。该过程在170℃的温度范围内进行。摄氏至500度C.,压力为1至250 bar,每小时空速为0.05至100 h。上文-1,在氢气的存在下,进料比例为50至2000 l / l。所得油具有良好的倾点和高粘度指数(VI)。该方法也适用于需要降低倾点的粗柴油和其他原料。还要求保护催化剂。

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