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Metallocene polyethylene blend compositions

机译:茂金属聚乙烯共混物组合物

摘要

An ethylene type polymer composition comprising 20 to 90% by weight of an ethylene type polymer (A) and 80 to 10% by weight of an ethylene type polymer (B). The ethylene type polymer (A) is an ethylene polymer or a copolymer of ethylene and an &agr;-olefin of 3 to 20 carbon atoms and has a density (d.sub.A) of 0.96 to 0.980 g/cm.sup.3 and an intrinsic viscosity (&eegr;) of 0.5 to 3.0 dl/g. The ethylene type polymer (B) is an ethylene polymer or a copolymer of ethylene and an . alpha.-olefin of 3 to 20 carbon atoms and has a density (d.sub.B) of 0. 91 to 0.965 g/cm.sup. 3 and an intrinsic viscosity (&eegr;) of 1.0 to 10 dl/g. At least one of the ethylene type polymers (A) and (B) is an ethylene type polymer prepared by the use of a metallocene catalyst. The ethylene type polymer composition has the properties: d.sub.A /d.sub.B is larger than 1; the density is 0.940 to 0.970 g/cm.sup.3 ; the MFR is of 0. 005 to 20 g/10 min; the MFR and the melt tension (MT) satisfy the relation log(MT)≧-0. 4 log(MFR)+0.7; and the diametrical swell ratio exceeds 1.35. From this composition, molded articles having excellent mechanical strength and rigidity can be obtained.
机译:乙烯型聚合物组合物,其包含20至90重量%的乙烯型聚合物(A)和80至10重量%的乙烯型聚合物(B)。乙烯类聚合物(A)是乙烯聚合物或乙烯与3至20个碳原子的α-烯烃的共聚物,并且密度(dA)为0.96至0.980g / cm 3且特性粘度(&eegr)为0.5至3.0dl / g。乙烯类聚合物(B)是乙烯聚合物或乙烯与乙烯的共聚物。具有3至20个碳原子的α-烯烃,密度(dB)为0. 91至0.965 g / cm 2。粘度为3,特性粘度(&eegr)为1.0至10dl / g。乙烯类聚合物(A)和(B)中的至少一种是通过使用茂金属催化剂制备的乙烯类聚合物。该乙烯类聚合物组合物具有以下特性:dA / dB大于1;密度为0.940至0.970 g / cm.sup.3; MFR为0。005至20g / 10min; MFR和熔体张力(MT)满足关系log(MT)≧ -0。 4 log(MFR)+0.7;直径膨胀比超过1.35。根据该组成,可以得到机械强度和刚性优异的成型品。

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