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Hydrolytically stable and polymerizable acrylic phosphonic acid

机译:水解稳定且可聚合的丙烯酸膦酸

摘要

Hydrolysis-stable and polymerizable acrylated mono- and diphosphonic acids, which are 2-(dihydroxyphosphoryl-oxa-alkyl)-acrylic acids or esters or corresponding bis compounds, and their stereoisomers and mixtures are new. Hydrolysis-stable and polymerizable acrylated mono- and diphosphonic acids, which are 2-(dihydroxyphosphoryl-oxa-alkyl)-acrylic acids or esters or corresponding bis compounds of formula (I), and their stereoisomers and mixtures are new; R1 = H, 1-10 carbon (C) alkyl or 6-10C aryl; R2 = H, F, 1-5C alkyl or phenyl; R3 = 1-8C alkylene or phenylene or is absent; Y = oxygen (-O-), sulfur (-S-), 1-8 C alkylene or is absent; n = 1 or 2; X = H, F, 1-5C alkyl or 6-12C aryl if n = 1; X = 1-10C alkylene, 6-10C arylene, 7-20C arylenealkylene or is absent if n = 2; The individual alkyl, aryl, alkylene, arylene, phenyl, phenylene and arylenealkylene groups may have substituent(s). Independent claims are also included for (a) (co)polymers obtained by (co)polymerization of (I); and (b) the preparation of (I).
机译:水解稳定且可聚合的丙烯酸酯化的单膦酸和二膦酸是2-(二羟基磷酰基-氧杂烷基)丙烯酸或酯或相应的双化合物,其立体异构体和混合物是新的。水解稳定且可聚合的丙烯酸单和双膦酸酯酸,是2-(二羟基磷酰基-氧杂-烷基)丙烯酸或酯或相应的式(I)双化合物,它们的立体异构体和混合物是新的。 R 1 = H,1-10个碳(C)烷基或6-10C芳基; R 2 = H,F,1-5C的烷基或苯基; R 3 = 1-8C亚烷基或亚苯基或不存在; Y =氧(-O-),硫(-S-),1-8个碳原子的亚烷基或不存在; n = 1或2;如果n = 1,则X = H,F,1-5C的烷基或6-12C的芳基; X = 1-10C亚烷基,6-10C亚芳基,7-20C亚芳基亚烷基或如果n = 2则不存在;各个烷基,芳基,亚烷基,亚芳基,苯基,亚苯基和亚芳基亚烷基可具有取代基。 (a)通过(I)的(共)聚合获得的(共)聚合物也包括独立权利要求; (b)(I)的制备。

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