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Optical addition reagent, reagent optical addition manner, and reagent optical addition device

机译:光学添加试剂,试剂光学添加方式及试剂光学添加装置

摘要

PROBLEM TO BE SOLVED: To enable many samples to be treated quickly, accurately, in a short time by using a cinnamate deriv. which has a double bond capable of causing trans-cis isomerization by light having a specified wavelength. ;SOLUTION: 10-30wt.% ε-aminocaproic acid bonded to a group represented by formula I (A), 10-30wt.% ω-aminoundecanoic acid bonded to a group represented by formula II (B), and polyphosphoric acid are sealed into a polymn. tube with its inside replaced with a nitrogen gas. The tube is heated, and then light obtd. by the combination with a cut-off filter transmitting light having wavelengths of 400nm of longer is radiated through optical fibers to the tube to cause the release, addition, and polymn. of component A. Simultaneously, light obtd. by the combination of a medium-voltage mercury lamp with a band pass filter selectively transmitting light having a wavelength of about 300nm is radiated through optical fibers to the tube to case the release, addition, and polymn. of component B. Since the intensity and time of light radiation can be controlled, the compsn. of the resultant copolycondensate of the above two acids can be selected from a very wide range.;COPYRIGHT: (C)1998,JPO
机译:解决的问题:使用肉桂酸酯衍生物可在短时间内快速,准确地处理许多样品。其具有能够通过特定波长的光引起反式-顺式异构化的双键。 ;解决方案:与式I(A)表示的基团键合的10-30wt。%ε-氨基己酸,与式II(B)表示的基团键合的10-30wt。%的ω-氨基十一烷酸和多磷酸被密封成一个polymn。管内部用氮气代替。加热管,然后熄灭。通过与截止滤光片结合使用,可以将更长波长为400nm的光通过光纤辐射到管中,从而引起释放,添加和多聚。同时,光线昏暗。通过将中压汞灯与带通滤光片结合使用,可选择性地传输波长约为300nm的光,并通过光纤辐射到灯管上,以防释放,添加和溶解。由于可以控制光辐射的强度和时间,因此该组合物可以被称为B。上面两种酸的共缩聚物的合成可以从很宽的范围内选择。版权所有:(C)1998,日本特许厅

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