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Production of base oil from hydrocarbon charging material, involves performing simultaneous hydrogenation and isomerization of charging material and contact deparaffination of the effluent under specific conditions

机译:由碳氢化合物装料生产基础油涉及在特定条件下同时进行装料的氢化和异构化以及废水的接触脱蜡

摘要

The method involves performing simultaneously hydrogenation and isomerization of charging material containing n-paraffin using a catalyst (I), and contact deparaffination of effluent using a second catalyst (II). Both the steps are performed at specific conditions. The method involves performing: (a) simultaneously hydrogenation and isomerization of charging material containing n-paraffin using a catalyst (I) containing noble metals precipitated on amorphous acid support; and (b) contact deparaffination of the effluent from step (a). The charging material contains less than 1000 ppm of sulfur, less than 200 ppm of nitrogen, less than 50 ppm of metal and 0.2 wt.% or less of oxygen. Step (a) is performed in the presence of hydrogen at 200-500[deg]C, a pressure of 2-25 MPa and a space velocity of 0.1-10/hour. The distribution of noble metal in the first catalyst (I) is 20-100%. Step (b) is performed at 200-500[deg]C, a pressure of 1-25 MPa, a space velocity of 0.05-50/hour and in the presence of a second catalyst (II) containing molecular sieve and hydrogenation-dehydrogenation component, and 50-2000 l of hydrogen per liter of effluent.
机译:该方法包括使用催化剂(I)同时进行含有正链烷烃的进料的氢化和异构化,以及使用第二催化剂(II)对流出物进行接触脱蜡。这两个步骤均在特定条件下执行。该方法包括:(a)使用含有沉淀在无定形酸载体上的贵金属的催化剂(I),同时使含有正链烷烃的进料材料氢化和异构化; (b)使步骤(a)的流出物接触脱蜡。充电材料包含少于1000ppm的硫,少于200ppm的氮,少于50ppm的金属和0.2重量%或更少的氧。步骤(a)在氢气存在下于200-500℃,2-25MPa的压力和0.1-10 /小时的空速下进行。在第一催化剂(I)中贵金属的分布为20-100%。步骤(b)在200-500℃,1-25MPa的压力,0.05-50 /小时的空速下并且在包含分子筛和氢化-脱氢的第二催化剂(II)的存在下进行。每升废水中含50-2000升氢气。

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