PVC polymerization with metered addition of emulsifiers

摘要

A process for preparing homo- and copolymers of vinyl chloride by batch polymerization in aqueous emulsion in the presence of an emulsifier combination comprising at least two emulsifiers selected from the class consisting of anionic and nonionic emulsifiers, metered in during the polymerization, which comprises metering-in in the first phase of the polymerization, at least one emulsifier of the emulsifier combination having at least 10 carbon atoms, and not starting to meter in the remaining emulsifiers of the emulsifier combination until a polymerization conversion of at least 10% has been reached.