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Method for manufacturing silicon compound having substituents bonded to silicon atoms via Si-C bonds
Method for manufacturing silicon compound having substituents bonded to silicon atoms via Si-C bonds
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机译:具有通过Si-C键与硅原子键合的取代基的硅化合物的制造方法
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摘要
A hydrosilylation reaction method that achieves high catalytic activity and stability, and improves the positional selectivity of the hydrosilylation reaction product. The method comprises reacting an unsaturated compound selected from the group consisting of aromatic vinyl compounds and allyl halides with a silicon compound having hydrosilyl groups described by formula HSiRn(Z)3−n, where n=0, 1, or 2, R is a hydrocarbon group and Z is selected from the group consisting of a silamino group, siloxy group, and siloxanoxy group in the presence of a carboxylic acid compound, a silyl ester of a sulfonic acid, and a platinum catalyst.
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机译:一种实现高催化活性和稳定性并提高氢化硅烷化反应产物的位置选择性的氢化硅烷化反应方法。该方法包括使选自由芳族乙烯基化合物和烯丙基卤组成的组的不饱和化合物与由式HSiR n Sub>(Z) 3&min; n Sub描述的具有氢甲硅烷基的硅化合物反应。 >,其中n等于0、1或2,R是烃基,并且Z在羧酸化合物的存在下选自由硅氨基,甲硅烷氧基和甲硅烷氧基组成的组,磺酸和铂催化剂。
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