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Method for inhibiting the degradation of hydrochlorofluorocarbons used as blowing agents in the production of foamed polyurethane and polyisocyanurate

机译:抑制在发泡聚氨酯和聚异氰脲酸酯生产中用作发泡剂的氢氯氟烃降解的方法

摘要

The invention relates to a method for inhibiting the degradation by dehydrohalogenation of hydrochlorofluorocarbons, such as for example the mixture of 123 and 123a, used as foaming agents during the formation reaction of foamed polyurethanes or polyisocyanurates starting from polyols and polyisocyanates. Prior to the reaction starting, a little amount of a stabilizing substance selected from the group consisting of nitromethane, nitroethane and 1-nitropropane is added to the reaction medium.
机译:本发明涉及一种通过氢氟氯烃的脱卤化氢来抑制降解的方法,所述氢氯氟烃例如是从多元醇和多异氰酸酯开始的发泡聚氨酯或多异氰脲酸酯的形成反应期间用作发泡剂的123和123a的混合物。在反应开始之前,将少量选自硝基甲烷,硝基乙烷和1-硝基丙烷的稳定物质加入到反应介质中。

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