halogen, -PO 3 R 12 R 13,-SO 3 R 14, -NO 2, hydrocarbyl, and R 1 and R 2, the substitution of -CO 2 R 15 except independently, R 15 and 13, R 14 R 7, R 8, R 9, R 12, R is the group consisting of cation is agronomically acceptable hydrogen, hydrocarbyl, and substituted hydrocarbyl; are selected from the group consisting of hydrocarbyl is selected from."/> By oxidation of N- replacement N- (phosphonomethyl) glycine N- (phosphonomethyl) glycine production method
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By oxidation of N- replacement N- (phosphonomethyl) glycine N- (phosphonomethyl) glycine production method

机译:通过氧化N-取代N-(膦酰基甲基)甘氨酸N-(膦酰基甲基)甘氨酸的生产方法

摘要

(57) (ie, "glyphosate") [Abstract] The present invention relates to an improved process for preparing esters of N- (phosphonomethyl) glycine and salts of N- (phosphonomethyl) glycine N- (phosphonomethyl) glycine. The method comprising placing in the presence of a noble metal catalyst, is reacted with oxygen, a substituted N- N- (phosphonomethyl) glycine reactants. N- replacement N- (phosphonomethyl) glycine reactant of the formula (V) [1] of At it is shown in the formula, independently, hydrogen, halogen, -PO 3 R 12 R 13,-SO 3 R 14, -NO 2, hydrocarbyl, and R 1 and R 2, the substitution of -CO 2 R 15 except independently, R 15 and 13, R 14 R 7, R 8, R 9, R 12, R is the group consisting of cation is agronomically acceptable hydrogen, hydrocarbyl, and substituted hydrocarbyl; are selected from the group consisting of hydrocarbyl is selected from.
机译:(57)(即“草甘膦”)。[摘要]本发明涉及一种制备N-(膦酰基甲基)甘氨酸的酯和N-(膦酰基甲基)甘氨酸N-(膦酰基甲基)甘氨酸的盐的改进方法。该方法包括将在贵金属催化剂存在下与取代的N-N-(膦酰基甲基)甘氨酸反应物与氧反应。式中的(V)[1]的N-取代N-(膦酰基甲基)甘氨酸反应物在式中独立地表示氢,卤素, -PO 3 R 12 R 13, -SO 3 R 14, -NO 2,烃基, R 1 R 2 取代 -CO 2 R 15 ,但独立地< Sup> R 15 13,R 14 R 7,R 8,R 9,R 12,R 是阳离子,其是农学上可接受的氢,烃基和取代的 >烃基; 选自由烃基组成的组。

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