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Asymmetric synthesis catalyzed by transition metal complexes with rigid chiral ligands
Asymmetric synthesis catalyzed by transition metal complexes with rigid chiral ligands
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机译:具有刚性手性配体的过渡金属配合物催化的不对称合成
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摘要
This invention is to develop novel transition metal catalysts for the practical synthesis of important chiral molecules. The invention emphasizes asymmetric catalysis based on chiral bidentate phosphine ligands with cyclic ring structures which could be used to restrict conformational flexibility of the ligands and thus the efficiency of chiral transfer can be enhanced through the ligand rigidity.
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