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ELECTROSTRICTIVE GRAFT ELASTOMERS

机译:静电接枝弹性体

摘要

An electrostrictive graft elastomer (11) has a backbone molecule (12) which is a non-crystallizable, flexible macromolecular chain and a grafted polymer (13) forming polar graft moieties with backbone molecules. The polar graft moieties have been rotated by an applied electric field, e.g., into substantial polar alignment. The rotation is sustained until the electric field is removed. A process for producing strain in an elastomer includes: (a) providing a graft elastomer having a backbone molecule which is a non-crystallizable, flexible macromolecular chain and a grafted polymer forming polar graft moieties with backbone molecules; and (b) applying an electric field to the graft elastomer to rotate the polar graft moieties, e.g., into substantial polar alignment. The backbone molecule is preferably chlorotrifluoroethylene-rinylidene fluoride copolymer, and the grafted polymer is poly vinylidene fluoride or a copolymer thereof.
机译:电致伸缩接枝弹性体(11)具有作为不可结晶的柔性大分子链的主链分子(12)和与主链分子形成极性接枝部分的接枝聚合物(13)。极性接枝部分已通过施加的电场旋转,例如转变为基本的极性排列。持续旋转直到去除电场。在弹性体中产生应变的方法包括:(a)提供具有主链分子的接枝弹性体,该主链分子是不可结晶的,柔性的大分子链和与主链分子形成极性接枝部分的接枝聚合物; (b)对接枝弹性体施加电场以使极性接枝部分旋转,例如旋转成基本上极性排列。骨架分子优选为三氟氯乙烯-亚偏氟乙烯共聚物,接枝聚合物为聚偏二氟乙烯或其共聚物。

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