首页> 外国专利> UNSATURATED SIDE CHAIN COMPOUND, PREPARATION METHOD THEREOF, LIQUID CRYSTAL POLYMER PREPARED FROM THE COMPOUND, LIQUID CRYSTAL MIXTURE AND DISPLAY ELEMENT

UNSATURATED SIDE CHAIN COMPOUND, PREPARATION METHOD THEREOF, LIQUID CRYSTAL POLYMER PREPARED FROM THE COMPOUND, LIQUID CRYSTAL MIXTURE AND DISPLAY ELEMENT

机译:非饱和侧链化合物,其制备方法,由该化合物,液晶混合物和显示元素制备的液晶聚合物

摘要

PURPOSE: An unsaturated side chain compound, its preparation method, a polysiloxane liquid crystal polymer prepared from the compound, ferroelectric a liquid crystal mixture and a liquid display element containing the mixture are provided, to obtain a material having an excellent impact resistance and showing liquid crystal phase at a wide range of temperature. CONSTITUTION: The polysiloxane liquid crystal polymer is obtained by graft polymerizing at least one compound selected from the group consisting of the compounds represented by the formulas 4 and 5 on polyalkylhydrosiloxane, wherein A and B are identical or different each other, and are 1,4-phenylene, 2,5-pyridine, 2,5-pyrimidine, 2,5-pyrazine, 3,6-pyridazine, 4,4'-biphenyl, 5-(2-phenylpyrimidine), 2-(5-phenylpyrimidine), 2-(5-phenylpyridine), 2,6-naphthalene, 2,6-quinoline, 2,6-quinoxaline or 2,6-quinazoline, or any one between A and B is a single bond; R1 is a saturated or unsaturated alkyl group of C1-C20 capable of being substituted with at least one halogen atom or an alkoxyalkyl group of C2-C20 capable of being substituted with at least one halogen atom; X is -CH2CH2-, -CH=CH- or a single bond; n is an integer of 0-6; q is an integer of 1-15; s is 0 or 1; * represents an asymmetric carbon atom; R6 is an alkyl, alkoxy, alkoxyalkyl or alkoxyalkyloxy group of C3-C20; j is an integer of 3-17; and t is 0 or 1.
机译:用途:提供一种不饱和侧链化合物,其制备方法,由该化合物制备的聚硅氧烷液晶聚合物,铁电液晶混合物和包含该混合物的液晶显示元件,以获得具有优异的耐冲击性和显示液体的材料。晶相在很宽的温度范围内。组成:聚硅氧烷液晶聚合物是通过在聚烷基氢硅氧烷上接枝聚合至少一种选自由式4和5表示的化合物的化合物而得到的,其中A和B彼此相同或不同,且为1,4 -亚苯基,2,5-吡啶,2,5-嘧啶,2,5-吡嗪,3,6-哒嗪,4,4'-联苯,5-(2-苯基嘧啶),2-(5-苯基嘧啶), 2-(5-苯基吡啶),2,6-萘,2,6-喹啉,2,6-喹喔啉或2,6-喹唑啉或A和B之间的任何一个为单键; R 1为能够被至少一个卤素原子取代的C 1 -C 20的饱和或不饱和烷基或能够被至少一个卤素原子取代的C 2 -C 20的烷氧基烷基。 X为-CH 2 CH 2-,-CH = CH-或单键; n是0-6的整数; q是1-15的整数; s是0或1; *代表不对称碳原子; R6是C3-C20的烷基,烷氧基,烷氧基烷基或烷氧基烷氧基; j是3-17的整数; t是0或1。

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