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Method for producing Philips catalyst for olefin polymerization having improved productivity by particle shape forming method

机译:通过颗粒形状形成方法生产具有提高的生产率的用于烯烃聚合的飞利浦催化剂的方法

摘要

In a process for producing Phillips catalysts in which an oxidic support material is treated in suspension with a chromium salt solution and subsequently, after removing the solvent, calcined in an oxygen-containing atmosphere at above 300° C., the oxidic support material and/or the catalyst after calcination are/is, according to the present invention, comminuted until a mean particle size of 100 mum has been reached and the proportion of particles having a size of 50 mum is at least 30%, preferably in the range from 40 to 80%. A process for preparing homopolymers or copolymers of ethene in a loop reactor at from 30 to 150° C. under a pressure in the range from 0.2 to 15 MPa in the presence of a catalyst produced by the process of the present invention is also provided.
机译:在生产菲利普斯催化剂的方法中,其中用铬盐溶液悬浮处理氧化载体材料,然后在除去溶剂之后,在高于300°C的含氧气氛中煅烧氧化载体材料和/根据本发明,将煅烧后的催化剂或煅烧后的催化剂粉碎,直至达到平均粒径<100μm,并且粒径<50μm的颗粒的比例为至少30%,优选在该范围内。从40%到80%。还提供了一种在环流反应器中在30至150℃,在0.2至15MPa范围内的压力下,在通过本发明的方法生产的催化剂的存在下制备乙烯的均聚物或共聚物的方法。

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