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ji - ( fluoro acrylic Acid) fluoro alkyl ester

机译:即 - ( 弗洛RO acrylic acid) 弗洛RO alky Lester

摘要

PURPOSE: To obtain a new di-(α-fluoroacrylic acid)fluoroalkyl ester useful as a raw material for forming a fluorine-containing cured film having a high surface hardness, a low refractive index, etc., and useful as a surface material for various kinds of base materials through a crosslinking polymerization. ;CONSTITUTION: A di-(α-fluoroacrylic acid)fluoroalkyl ester represented by formula I (X is a 2 to 14C fluoroalkyl having three or more fluorine atoms or a 4 to 14C fluorocycloalkyl having four or more fluorine atoms), e.g. di-(a- fluoroacrylic acid)-2-2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-heptadecafluorononylethylene glycol of formula II. The compound of formula I can be synthesized, e.g. by conducting a ring-opening reaction between a fluorine-containing epoxy of formula III and an α-fluoroacrylic acid in the presence of a catalyst to obtain an α- fluoroacrylic acid hydroxyfluoroalkyl ester of formula IV and an α-fluoroacrylic acid hydroxyfluoroalkyl ester of formula V and then conducting an esterification reaction.;COPYRIGHT: (C)1995,JPO
机译:用途:获得新的二-(α-氟丙烯酸)氟代烷基酯,用作形成具有高表面硬度,低折射率等的含氟固化膜的原料,并可用作表面材料用于各种基础材料的交联聚合。组成:式I表示的二-(α-氟代丙烯酸)氟代烷基酯(X是具有三个或更多个氟原子的2至14C氟代烷基或具有四个或更多个氟原子的4至14C氟代环烷基),例如式II的二-(α-氟代丙烯酸)-2-2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-十七碳氟壬基乙二醇。可以合成例如式I的化合物。通过在催化剂的存在下在式III的含氟环氧树脂与α-氟代丙烯酸之间进行开环反应以获得式IV的α-氟代丙烯酸羟基氟代烷基酯和α-氟代丙烯酸羟基氟代烷基式Ⅴ的酯,然后进行酯化反应。;版权所有:(C)1995,日本特许厅

著录项

  • 公开/公告号JP3374494B2

    专利类型

  • 公开/公告日2003-02-04

    原文格式PDF

  • 申请/专利权人 日本油脂株式会社;

    申请/专利号JP19930333318

  • 发明设计人 吉田 達朗;天谷 直之;

    申请日1993-12-27

  • 分类号C07C69/653;C08F20/68;

  • 国家 JP

  • 入库时间 2022-08-22 00:18:22

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