Method of producing tungsten-copper based composite powder and sintered alloys for heat-sink using said composite powder

摘要

The present invention relates to a method of producing WCu based composite powder, which is used in heat-sink materials for high-power integrated circuits, electric contact materials, etc, and to a method of producing a WCu based sintered alloy by using the composite powder. The method of producing tungsten-copper based composite powder includes first preparing composite oxide powder by dissolving ammonium metatungstate, (NH₄)₆(H₂W₁₂O₄₀).4H₂O, as water-soluble tungsten salt, and copper nitrate or copper acetate in water to the desirable composition, followed by spray-drying and calcining; then preparing a tungsten oxide powder by separately calcining a tungsten-containing salt, such as ammonium paratungstate, (NH₄)₁₀(H₁₀W₁₂O₄₆); forming ultra-fine tungsten-copper based composite oxide powder by mixing 2075wt % of the composite oxide powder and 8025wt % of the tungsten oxide powder to the desirable composition, followed by ball-milling; and reducing the ultra-fine tungsten-copper based composite oxide powder at temperature of 6501,050 C. If the composite powder is molded into a certain size and sintered thereafter in temperature of 1,1101,450 C., a WCu based sintered alloy of superior thermal and electric conductivities can be obtained thereby.