首页>
外国专利>
Ruthenium metal alkylidene complexes coordinated with triazolylidene ligands that exhibit high olefin metathesis activity
Ruthenium metal alkylidene complexes coordinated with triazolylidene ligands that exhibit high olefin metathesis activity
展开▼
机译:钌金属亚烷基络合物与表现出高烯烃复分解活性的三唑亚基配体配合
展开▼
页面导航
摘要
著录项
相似文献
摘要
The invention discloses ruthenium alkylidene complexes of the type (PCy3)(L)Cl2Ru(CHPh), where L is a triazolylidene ligand of the general formula: ;These catalysts have been found to be considerably more active for olefin metathesis at elevated temperatures than the parent catalyst (PCy3)2Cl2Ru(CHPh)(2). For example, complex 14 (L=1,3,4-triphenyl-4.5-dihydro-1H-triazol-5-ylidene) is able to catalyze the ring-closing metathesis of substituted dienes to give tetra-substituted cyclic olefins in good yield. In addition, this complex demonstrates the analogous stability towards oxygen and moisture exhibited by ruthenium alkylidene 2.
展开▼
机译:本发明公开了类型为(PCy 3 Sub>)(L)Cl 2 Sub> Ru(CHPh)的钌亚烷基络合物,其中L为通式的三唑基亚烷基配体: id =“ CHEM-US-00001”> <图像alt =“嵌入式图像” file =“ US06624265-20030923-C00001.GIF” he =“ 47.99655” id =“ EMI-C00001” imgContent =“ undefined” imgFormat =“ GIF “ wi =” 65.9988“ /> Chemistry>;已发现这些催化剂在高温下的烯烃复分解活性比母体催化剂(PCy 3 Sub >) 2 Sub> Cl 2 Sub> Ru(CHPh)(2)。例如,配合物14(L等于1,3,4-三苯基-4.5-二氢-1H-三唑-5-亚烷基)能够催化取代的二烯的闭环复分解反应,从而以高收率得到四取代的环烯烃。 。此外,该络合物还显示出亚烷基钌2对氧气和湿气的类似稳定性。
展开▼