Temperature measurement and temperature controlled switching based on helical sense dependent liquid crystal phases

摘要

Helical arrays comprising structurally different chiral non-racemic molecules or molecular entities that control the helical sense of the helical array provide a method for temperature measurement with a unique characteristic in that the temperature dependent chiral biases of the competing structurally different chiral non-racemic entities control the helical sense population since these biases differ in their temperature dependence. By varying the composition of the chiral non-racemic entities, the temperature at which the helical sense population is equal and how the helical sense population varies as a function of temperature can be controlled. In this way, competing structurally different non-racemic chiral groups can be varied in their composition so that a helical array can be formed under their effect and be sensitive to temperature over a wide temperature range. The resulting material, which can be used as a temperature measuring material or as a switch depending on fast reversible temperature changes, can be used in the context of a plastic unit, liquid displays, liquid crystals, and the like.