Ethers herbicides vinilarilo Properties, compositions and Products made with such Compounds; methods for controlling weeds in a place with such compositions, Methods for reducing the Phytotoxicity of these compounds on grasses and processes for preparing the composed

摘要

It is arilvinu00edlio ethers of General formula (1), where p is 0 OR 1, X1 is o or s, NH; x2 is o, s or n, NR18 single link; X3 is n or cr19 R17 and R18; independently represent a hydrogen Atom or a group R20 R21, R22, or R23 optionally replaced,In which represents a Lower alkyl radical: R20 R21, R22 represents a radical alquenilo represents a radical alquinilo Bottom; Bottom; R23 represents a radical - phenyl - (CH2) m; M represents Zero or one; or or25 R16 is R24 or sr25r26 or alkyl substituted with R24, alcoxicarbonilo;R25, R26 independently one of the meanings given to R18; R19 is one of the meanings given to R16; R10 represents a radical selected from: ch2no2 chr27r28 cr27r28r28 ', -, -, - cr30r29r29', co nr30r31 ch2nr30r31 -, -, - ch = cr31r32, - ch2n (R30) s (or qr33), - C (o) - sr32, CH2C sr32, (OR) - (CH2) zco2r32, co2r32 -, - ch = cHC (OR) or32 (R32), - C = N - nr30r31 (R32), - C = N - NH - C (o) - Lower alkyl,Cor32 -, - C (o) (or OC) R32, - C = N -) csccoor32 ch2scn R32, -, -, - ch2nco ch2ncs ch2n3 -, -, -, - ch2cn, ch2oscn, ch2ocn, - ch2n (R30) co2r33 ch2oso2r33 ch2so2or33, -, -, - ch2oco2r33, Ch chnr33r34 =, - C (o) - C (= onr33r34, R32, ch2p nr35) - (OR) - r35r36, ch2op r35r36 - ch2oc (OR), (OR) nr30r36, ch2och2c - (OR) - (phenyl optionally its - co2n Structures), c = - 2 (optionally substituted phenyl) - n, N - succinimidometilo, ftalimidometilo,A Group tetrazolilo (especially tetrazolilo conhnhr30 1 -, -, -) co2ch2co - (phenyl optionally substituted Heterocyclic ring, or a saturated or unsaturated 5-7 members containing 1-3 hetero Atoms selected from o, N and S) - co2ch2 - (saturated or unsaturated Heterocyclic Ring of 5 - 7. Bros containing 1-3 hetero Atoms selected from o, N and S), co2r32a, coch2cor33, cochn2,- (substituted with lower alkyl hydroxyl), CH (OR) - (Lower alkyl), C (R32) - NH - n = C (S) = C (R32) NRA, NH - N - (optionally substituted unsaturated Heterocyclic Ring containing 5-7 members selected Atoms of 1 - 3 o, N and S), C (R32) - nr30ar31a = N, c = N - nhso2r33 (R32) and C (o) F Z represent; One, two,Three or four; Q represents Zero or two; ra represents H or alkyl imidazole r32a represents a lower bound; n, optionally substituted, or optionally a condensate with a triazole ring and benzene Ring; r30a r31a, together with the atom of n that are United to form a ring, I Terocu00edclico saturated with 5 or 6 members, which contains an optional, orNRA in Group s or additional Ring; R27, R28 and R281 represent the same or different Halogen Atoms; r291 R29 and represent or37 or sr37 or r291 R29, and together form a divalent radical, which with the carbon Atom to which they are United to form a cyclic acetal Ring or tioacetal 5 6 members,The Ring system is optionally substituted with one or more alkyl groups Lower R30, R31, R32 and independently represent Hydrogen, Lower alkyl, haloalquilo alkoxyalkyl Esters Lower, Lower, Lower alquenilo, haloalquenilo alquinilo Lower, Lower, Lower haloalquinilo Cycloalkyl, optionally substituted,- (CH2) M - phenyl optionally substituted; R33 and R34 represent R32 to the exclusion of the atom of hydrogen; R36 R35 and represent a hydrogen Atom or a radical which can be any of the following: alkoxy or alkyl, optionally substituted phenyl; R37 represents Lower alkyl, halo Lower alkyl,Alquenilo lower or lower haloalquenilo; R11 and R13 each independently represent Hydrogen or alkyl, or R11 and R13 can be together for a single link that creates a double bond with the carbon Atom to which they are United, R11 and R13 or may be only a divalent radical, which includes E one or six Atoms in the main ChainMain chain is optionally containing one to three nitrogen ATOMS, one Oxygen Atom or a Sulfur Atom; forming the divalent radical with two carbon Atoms to which it is attached, a carbocu00edclico Ring or Heterocyclic Ring or a saturated or unsaturated bicyclic These rings are optionally substituted with one to four radical R15Each containing up to eight Member Ring by ring, preferably at most Six R15, which represents a Halogen Atom, a Lower alkyl, cyano, alcoxicarbonilo alquenilo, Lower, Lower, Lower alquinilo, cycloalkyl, optionally substituted alkoxy inferi Or, Alquiltio alquilsulfinilo Lower, Lower, Lower alquilsulfonilo,Haloalcoxicarbonilo haloalquilo Lower, Lower, Lower haloalquenilo, haloalquinilo halocicloalquilo haloalcoxi Lower, Lower, Lower haloalquiltio haloalquilsulfinilo haloalquilsulfonilo, Lower, Lower, Lower alquilamino, Nitro, amino, dialquilamino Lower opcionalm phenoxy Being replaced, alquilcarbonilamino alquilcarbamoilo carbamoilo, Lower, LowerCh2scn dialcyl carbamoyl -, Lower - sedan, cr30 = N - cr30 R31 - = - = nor31, cr30 nnr30r31, - cr30r29r291, alkoxyalkyl esters, crbrcra, Cora, or optionally substituted phenyl, naphthyl, or alqueniloxi replaced with alcoxicarbonilo or CO2H; RB and RC, along with the C Atoms to which they are United form a g Cyclic acetal Group of 5 or 6 members; or r10r11r12c - C (R13) (R14) - represents a Group (a), (b), (c),(d) or (e): the RF, RD, re, RG and represent LOWER RH h, alkyl, halogen or Oh, and N represents the values 0, 1, 2, or 3, R151 represents a hydrogen Atom or R15, R14 R12 and each independently represent Hydrogen or alkyl a simple Link, or May form, creating a e Double nlace together when R11 and R13 are togetherA single Bivalent radical; preferably with the following conditions: (i) when r10r11r12c - C (R13) (R14) represents an optionally substituted - phenyl Ring with R15, R10 represents u00fbco2r32, conr30r11, chr27r28 or cr27r28r281 R32, which represents alkyl or haloalquilo R30, R31 and repres They H or alkyl, R27,R28 and R281 are as defined above, p is Zero; x1 or x2 or X3 is; is; CH; R16 is or25 R15; then is not a Group monohalometilo; (ii) when r10r11r12c - C (R13) (R14) represents a Group eto2c - ch = CH - p is 1; S; x1; x2 is a Link; R17 represents phenyl; X3 is CH NH2 R16; then it is not Or Nme2; (iii) when R11, R12, R13,R14 represents each h; p is 1; S x1; x2 is or represents et; R17, X3 is n; R16 represents u00fbnh (4-nitrophenyl); or conhph R10 is not CO2H; (iv) when R11, R12, R13,R14 represents each h; p is Zero; x1; x2 is or represents R17; et; X3 is n; R16 represents u00fbnh (4-nitrophenyl); or CONH2 R10 is not CO2H; (V) when p is Zero; x1 or x2 is a Link; R17 represents h; X3 is; CH; R16 represents Nme2; r10r11r12c - C (R13) (R14) - represents a group 5 - meti L - 2 - R10 Tien - 3 - ilo replaced; R10 is not CO2H or co2me; (VI) when R11, R12,R13 and R14 represents each h; p is Zero; x1 is s; x2 or X3 is R17 represents; h; n; R16 represents u00fbnh (4nitrofenilo R10 is not CO2H);; (vii) represents co2et R10, R11, R12, R13, R14 represents each h; p is Zero; x1 is s; X2 is NH; R17 represents X3 is phenyl; CME; R16 is NH2 or n EHR; and (viii) when p is Zero; x1 or x2 is or represents R17;; I; X3 is CHR16 represents OME; r10r11r12c - C (R13) (R14) - represents a group 1,3 Dimethyl pyrazole - R10 - 4 - 5 - ILO - R10 is not replaced; 4 - clorobenzoilo; and agriculturally acceptable Salts and metal complexes thereof. Also prepare the objects referred to in the title.