Fenilalquinos herbicidamente assets composition, Process for its preparation, herbicide and Plant Growth inhibitory, procedure to control the growth of unwanted plants and a method for inhibiting the growth of Plants

摘要

Fenilalquinos that has the formula (1), in which n is 0, 1, 2, 3 or 4; each R1 is independently, halogen, - CN, - SNA, sedan, - NO2 - nr5r6 co2r7 conr8r9, -, -, - C (R10) = nor11, - cor12 OR13 SR14, -, -, - sor15, so2r16 -, alkyl - oso2r17 C1, C2 alquenilo - 8 - 8 - 8 or cicloal alquinilo C2 Chyle C3 - 6 or - C1 represents alkyl; 8Alquenilo C2 or C2 - 8 - 8 alquinilo substituted with one or more substituents of the Halogen Series, - CN, - NO2, nr18r19 co2r20 -, -, - conr21r22, cor23 -, - C (= nor25 R24), C - (S) - C (nr26r27, c1-4 alkyl - Uncle) = nr28 or29 SR30, -, -, - sor31, so2r32 or cycloalkyl - C3 - 6; or each R1 is cycloalkyl substituted with C3 - 6 One or more of the Halogen substituents would be, - CN, - NO2 - nr18r19 co2r20 conr21r22, -, -, - cor23,Nor25 (R24) - C = (S, c) - C (nr26r27, c1-4 alkyl - Uncle) = nr28, - 30, - sor31, so2r32 or cycloalkyl - C3 - 6; or each R1 is independently, phenyl, which in turn can be replaced with one or more the number of halogen substituents, c1-4 alkyl, alkoxyl haloalquilo C1 C1 - 4, - 4, - CN, - NO2, Lquil C1 - 4 - Uncle- sulfinilo c1-4 alkyl or alkyl sulfonyl or C1 - 4 - R2; two adjacent together form a Bridge alquileno C1 - 7, which can be disrupted by 1 or 2 non adjacent Oxygen Atoms that can be substituted with alkyl and C1 - 6, the total number of Atoms in the Ring for you Meno S 5 and a maximum of 9; or two adjacent R1 together form a Bridge alquenileno C2 - 7That can be disrupted by 1 or 2 non adjacent Oxygen Atoms that can be substituted with alkyl and C1 - 6, the total number of Atoms of the Ring at least 5 and a maximum of 9; R3 and R4 are each, independently, Hydrogen, halogen, CNC1-4 alkyl or alkoxyl c1-4; R3 and R4 represent alquileno C2 - 5; R5 is Hydrogen or alkyl of C1 - 8; R6 is Hydrogen, alkyl alquenilo C1 - C3 - 8, 8, 8 alquinilo C3 -, phenyl or benzyl; being the phenyl and benzyl substituted turn with one or more substituents of the S Erie c1-4 alkyl, halogen, alkoxyl haloalquilo C1 C1 - 4, - 4, - CN, - NO2, c1-4 alkyl - Uncle- sulfinilo c1-4 alkyl or alkyl sulfonyl or - C1 - 4; R5 and R6 represent a Chain of alquileno C2 - 5, which can be interrupted by an oxygen or Sulphur Atom; R7 is Hydrogen, alkyl alquenilo C3 C1 - 8 - 8 - 8 or alquinilo C3 alkyl, or C1 - 8 alquenilo C3, C3 - 8 - 8 or alquinilo Substituted with one or more substituents of the Halogen Series,C1-4 or alkoxyl phenyl; and in turn the phenyl substituted with one or more substituents of the Halogen Series, haloalquilo c1-4 alkyl, alkoxyl C1 C1 - 4, - 4, - CN, - NO2, c1-4 alkyl - Uncle, c1-4 alkyl - or sulfinilo c1-4 alkyl - is Hydrogen or alkyl sulfonyl; R8 R9 represents c1-4; Hydrogen C1 - 8 or alkyl or alkyl substituted C1 - 8 with one or more substituents of the series - COOH,Alkoxy carbonyl C1 - 8 or - ns; or alquenilo R9 is alquinilo C3 C3 - 8 - 8, phenyl or benzyl; being the phenyl and benzyl in turn substituted with one or more substituents of the Halogen Series, haloalquilo c1-4 alkyl, alkoxyl C1 C1 - 4, - 4, - CN, - NO2, c1-4 alkyl - Uncle, c1-4 alkyl - or sulfinilo Lquil C1 - 4 - sulfonyl; or represent alquileno R8 and R9 R10 is C2 - 5; HydrogenC1-4 alkyl, cycloalkyl or haloalquilo C1 - C3 4 - 6; R11 is Hydrogen, alkyl alquenilo C3 C1 - 8 - 8 - 8 haloalquilo alquinilo, C3, C1 - C3 - 4 or 6 haloalquenilo; R12 is Hydrogen, c1-4 alkyl, cycloalkyl or haloalquilo C1 - C3 4 - 6; R13 is Hydrogen, alkyl alquenilo C3 C1 - 8 - 8 - 8 or alquinilo C3; or R13 is phenyl alkyl or phenyl - C1 - 6The phenyl Ring can be replaced with one or more substituents of the Halogen Series, haloalquilo c1-4 alkyl, alkoxyl C1 C1 - 4, - 4, - CN, - NO2 or - S (o) 2alquilo C1 - 8; R13 is C1 - 8 or alkyl substituted with one or more substituents from the series - CN or Halogen, alkoxyl c1-4, R14 s Means Hydrogen, alkyl alquenilo C3 C1 - 8 - 8 - 8 or alquinilo C3,C1 - 8 or alkyl substituted with one or more substituents of the series - CN or Halogen, alkoxyl c1-4, R15 and R16, R17 are each, independently, alquenilo C1 C3 alkyl - 8 - 8 - 8 or alquinilo C3, C1 - 8 or alkyl substituted with one or more substituents of the Halogen Series, - CN, or Lcoxilo c1-4, R18 is Hydrogen or alkyl of C1 - 8; R19 is Hydrogen, alkyl alquenilo C1 - C3 - 8 8Alquinilo C3 - 8, phenyl or benzyl; being the phenyl and benzyl in turn substituted with one or more substituents of the Halogen Series, haloalquilo c1-4 alkyl, alkoxyl C1 C1 - 4, - 4, - CN, - NO2, c1-4 alkyl - Uncle, c1-4 alkyl - sulfinilo or c1-4 alkyl Sulfonyl - or R18 and R19 represent Group; Once a Chain of alquileno C2 - 5That can be interrupted by an oxygen or Sulphur Atom; R20 is Hydrogen, alkyl alquenilo C1 - C3 - 8, 8, 8 alquinilo C3 -, phenyl or benzyl; being the phenyl and benzyl in turn substituted with one or more substituents of the Halogen Series, c1-4 alkyl, haloalquilo C1 - 4, alcox ILO C1 - 4, - CN, - NO2, c1-4 alkyl - Uncle- sulfinilo c1-4 alkyl or alkyl sulfonyl R21 - 4 - C1, C1 represents Hydrogen or alkyl - 8; R22 represents Hydrogen or alkyl or alkyl C1 C1 - 8 - 8 substituted with one or more substituents of the series - COOH, - 8 - alkoxy carbonyl or C1 - C3 represents alquenilo R22 ns; or - alquinilo C3 - 8 8PHENYL or benzyl; being the phenyl and benzyl in turn substituted with one or more substituents of the Halogen Series, haloalquilo c1-4 alkyl, alkoxyl C1 C1 - 4, - 4, - CN, - NO2, c1-4 alkyl - Uncle, c1-4 alkyl - or sulfinilo c1-4 alkyl - sulfonyl; or represent alquileno R21 and R22 C2 - 5; R23 is Hydrogen, c1-4 alkyl, cycloalkyl haloalquilo C1 - C3 - 4 or 6 R24 is Hydrogen;C1-4 alkyl or cycloalkyl c3-6 R25 means; Hydrogen, alkyl alquenilo C3 C1 - 8 - 8 - 8 haloalquilo alquinilo, C3, C1 - C3 - 4 or 6 haloalquenilo; R26 represents Hydrogen or alkyl of C1 - 8; R27 represents Hydrogen or alkyl or alkyl C1 C1 - 8 - 8 replaced one or more substituents of the Series - Coo H, or C1 - 8 - alkoxy carbonyl - ns; or alquenilo R27 represents 8 alquinilo C3, C3 - 8PHENYL or benzyl; being the phenyl and benzyl in turn substituted with one or more substituents of the Halogen Series, haloalquilo c1-4 alkyl, alkoxyl C1 C1 - 4, - 4, - CN, - NO2, c1-4 alkyl - Uncle, c1-4 alkyl - or sulfinilo c1-4 alkyl - sulfonyl or R26, R27, together represent alquileno C2 - 5 represents Hydrogen or alkyl R28, R29, R30 C1 - 8; mean each,Independently Hydrogen, alkyl, 8 alquenilo C1 - C3, C3 or alquinilo - 8 - 8 - 8 C1 or alkyl, substituted with one or more substituents of the series - CN or Halogen, alkoxyl c1-4, R31, R32 and are each, independently, alkyl C1 - C3 - 8, alquenilo alquinilo C3 - 8 or 8, or Lquilo C1 - 8 substituted with one or more substituents of the series Halogen, alkoxyl C1 cn or 4; M is 0,1, 2, 3, 4 or 5; each R2 means independently, halogen, - CN, - SNA, sedan, - NO2 - nr36r37 co2r38 conr39r40, -, -, - C (R41) = nor42 cor43 or44, -, -, - - - so2r47 sor46 SR45,,, - oso2r48, N - ([co] cor50 pr49), - N (or51) cor52 (R53) - n, N - or - co2r54 Phthalimide; R36 is Hydrogen or alkyl of C1 - 8; R37 signi Is Hydrogen, alkyl alquenilo C3 C1 - 8 - 8 - 8 alquinilo C3,PHENYL or benzyl; being the phenyl and benzyl in turn substituted with one or more substituents of the Halogen Series, haloalquilo c1-4 alkyl, alkoxyl C1 C1 - 4, - 4, - CN, - NO2, c1-4 alkyl - Uncle, c1-4 alkyl - or sulfinilo c1-4 alkyl - sulfonyl R36; or represent a Caden and R37 To alquileno C2 - 5That can be interrupted by an oxygen Atom or a Sulfur R38 means; Hydrogen, alkyl alquenilo C3 C1 - 8 - 8 - 8 or alquinilo C3, C1 or C3 alkyl alquenilo - 8 - 8 - 8 alquinilo C3 or substituted by one or more substituents of the series Halogen, alkoxyl phenyl or C1 - 4 being the FENI; This, in turn, replaced with one or more substituents of the Halogen Series, c1-4 alkyl,Haloalquilo alkoxyl C1 C1 - 4, - 4, - CN, - NO2, c1-4 alkyl - Uncle, c1-4 alkyl - or sulfinilo c1-4 alkyl sulfonyl is Hydrogen or - alkyl; R39 R40 C1 - 8; represents Hydrogen or alkyl or alkyl C1 C1 - 8 - 8 replaced with one or more substituents of the series - COOH, - 8 - or alkoxy carbonyl C1 cn or R40 alq is; Uenilo alquinilo C3 C3 - 8 - 8PHENYL or benzyl; being the phenyl and benzyl in turn substituted with one or more substituents of the Halogen Series, haloalquilo c1-4 alkyl, alkoxyl C1 C1 - 4, - 4, - CN, - NO2, c1-4 alkyl - Uncle, c1-4 alkyl - or sulfinilo c1-4 alkyl - sulfonyl or R39 and R40, together represent alquileno C3 - 5; R41 is Hydrogen, c1-4 alkyl, cycloalkyl haloalquilo C1 - C3 - 4 or 6 R42 means; HydrogenAlquenilo C1 C3 alkyl - 8 - 8 - 8 haloalquilo alquinilo, C3, C1 - C3 - 4 or 6 haloalquenilo; R43 Hydrogen, c1-4 alkyl, cycloalkyl or haloalquilo C1 - C3 4 - 6; R44 is Hydrogen, alkyl alquenilo C3 C1 - 8 - 8 - 8 or alquinilo C3; or R44 is phenyl alkyl or Phenyl - C1 - 6, the phenyl Ring can be Substituted with one or more substituents of the Halogen Series, c1-4 alkyl,Haloalquilo alkoxyl C1 C1 - 4, - 4, - CN, - NO2 or - S (o) 2alquilo C1 - 8; R44 is C1 - 8 or alkyl substituted with one or more substituents of the series - CN or Halogen, alkoxyl c1-4 alkyl; R45 is Hydrogen, C1 - C3 - 8, alquenilo 8 or alquinilo C1 or C3 - 8 - 8 alkyl, substituted with one or more substituents of the CN series Halogen, alkoxyl or c1-4, R46, R47 and R48 are each, independently,Alquenilo C1 C3 alkyl - 8 - 8 - 8 or alquinilo C3, C1 - 8 or alkyl substituted with one or more substituents of the series - CN or Halogen, alkoxyl c1-4, p is 0 OR 1; R49, R50, R51, R52 R53 R54, and are each, independently, Hydrogen, alkyl or phenyl C1 - 8 can be; Turn replaced with one or more alkyl substituents of the Halogen Series, haloalquilo C1 C1 - 8 - 4Alkoxyl C1 - 4, - CN, - NO2, c1-4 alkyl - Uncle, c1-4 alkyl - or sulfinilo c1-4 alkyl Sulfonyl -; or each independently, R2, C1 represents alkyl or alkyl of C1 - 8 - 8 mono - or pol