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BICYCLIC PHOSPHIN COMPRISING HYDROFORMYLATION CATALYST AND USE THEREOF IN PRODUCTION OF OXYGENATED PRODUCTS

机译:包含加氢甲酰化催化剂的双环膦及其在加氧产品生产中的用途

摘要

Title: PRODUCTION OF OXYGENATED PRODUCTS[err]Abstract: A process for producing oxygenated products from an olefinic feedstock, which process includes reacting, in a hy-droformylation reaction stage, an olefin feedstock with carbon monoxide and hydrogen at elevated temperature and superatmospheric pressure in the presence of a hydroformylation catalyst. The hydroformylation catalyst comprises a mixture of a metal, M, where M is cobalt (Co), rhodium (Rh), ruthenium (Ru) or palladium (Pd); carbon monoxide; and a bicyclic tertiary phosphine having a ligating phosphorus atom. The ligating phosphorus atom is neither in a bridgehead position nor a member of a bridge linkage. The process produces oxygenated products comprising aldehydes and/or alcohols.
机译:标题:含氧产品的生产[呃]摘要:一种由烯烃原料生产含氧产物的方法,该方法包括在氢氢甲酰化反应阶段,是在高温和超大气压下与一氧化碳和氢气混合的烯烃原料在加氢甲酰化催化剂存在下的高压。加氢甲酰化催化剂包含金属M的混合物,其中M为钴(Co),铑(Rh),钌(Ru)或钯(Pd);一氧化碳;和具有环氧基的双环叔膦连接磷原子。连接的磷原子既不在桥头位置也不在桥键的成员上。的该方法产生包含醛和/或醇的氧化产物。

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