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PREPARATION OF AROMATIC AMINES THROUGH NEW HYDROGENATION CATALYSTS.
PREPARATION OF AROMATIC AMINES THROUGH NEW HYDROGENATION CATALYSTS.
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机译:通过新型加氢催化剂制备芳族胺。
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摘要
The invention relates to aromatic amines that are manufactured by the corresponding catalytic hydrogenation of aromatic nitro compounds in the gas phase. Hydrogenation is carried out in the presence of a catalyst containing palladium, vanadium and lead as well as rhenium in a ceramic carrier with a BET surface of less than 40 m {sup, 3} / g at temperatures ranging from 180º to 500ºC in the catalyst support and with a molar ratio of H to variable nitro groups from 3: 1 to 30: 1.
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机译:本发明涉及芳族胺,其通过在气相中芳族硝基化合物的相应催化氢化来制备。在催化剂表面上BET表面小于40 m {sup,3} / g的陶瓷载体中,在含钯,钒和铅以及rh的催化剂存在下,在催化剂的180º至500ºC温度下进行氢化反应H与可变硝基的摩尔比为3:1至30:1。
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