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Photographic elements containing cyan dye-forming coupler having a sulfone ballast group

机译:包含具有砜镇流剂基团的形成青色染料的成色剂的照相元件

摘要

A photographic element comprises a light sensitive silver halide emulsion layer having associated therewith a cyan dye forming coupler having Formula (I):    whereinR1 represents hydrogen or an alkyl group;R2 represents an alkyl group or an aryl group;n represents 1, 2, or 3;each X is located at a position of the phenyl ring meta or para to the sulfonyl group and is independently selected from the group consisting of alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulfonyloxy, sulfamoylamino, sulfonamido, ureido, oxycarbonyl, oxycarbonylamino, and carbamoyl groups; andZ represents a hydrogen atom or a group which can be split off by the reaction of the coupler with an oxidized color developing agentprovided that when R1 is an alkyl group of 4 or more carbon atoms, R2 is a phenyl group which has an electron withdrawing group having a Hammett's Sigma value greater than 0 in a position meta or para to the amido group and has no group having a Hammett's Sigma value greater than 0 in a position ortho to the amido group.;The element forms a dye upon development which has a desirably low wavelength of maximum absorbance and low unwanted green absorbance.
机译:摄影元件包括光敏卤化银乳剂层,其与具有式(I)的形成青色染料的成色剂相关联: 其中 R 1 表示氢或烷基; R 2 < / Sub>表示烷基或芳基; n表示1、2或3; 每个X位于苯环的间位或对位磺酰基,并且独立地选自烷基,烯基,烷氧基,芳氧基,酰氧基,酰氨基,磺酰氧基,氨磺酰氨基,磺酰胺基,脲基,氧羰基,氧羰基氨基和氨基甲酰基。并且 Z表示氢原子或可通过成色剂与氧化的彩色显影剂反应分离出的基团 ,前提是当R 1 是具有4个或更多个碳原子的烷基,R 2 是在酰胺基的对位或对位具有吸电子基团的苯基,该吸电子基团的哈米特西格玛值大于0 <!-EPO ->;该元素形成一个染料在显影时具有期望的最大吸收波长和低的不希望的绿色吸收波长。

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