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FLUOROCHEMICAL COMPOSITION CONTAINING A CONDENSATION PRODUCT OF A FLUOROCHEMICAL POLYETHER AND A POLY-ISOCYANATE TO IMPART STAIN RELEASE PROPERTIES TO A SUBSTRATE
FLUOROCHEMICAL COMPOSITION CONTAINING A CONDENSATION PRODUCT OF A FLUOROCHEMICAL POLYETHER AND A POLY-ISOCYANATE TO IMPART STAIN RELEASE PROPERTIES TO A SUBSTRATE
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机译:含氟化学聚合物和聚异氰酸酯的缩合产物的含氟化学成分,可将污渍的释放性能赋予基质
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摘要
This invention discloses a fluorochemical composition comprising a condensation product of a diisocyanate or triisocyanate and at least one polyether obtainable by reacting a fluorochemical substituted epoxide of formula (I) with a compound of formula (II) HX1-B-X2H or (III) (R¿f?')k-L?2-X2¿H wherein: B represents an organic residue obtained by removing the groups HX?1 and HX2¿ from the compound in formula (II); X?1 and X2¿ are each independently selected from the group consisting of O, NH and S; L1 represents an organic divalent linking group; L2 represents an organic linking group having a valence of k+1; k is an integer of 1 to 10; R¿f? and Rf' are each independently selected from the group consisting of perfluorinated and partially fluorinated aliphatic groups; s is 0 or 1; and a is 0 or 1. The fluorochemical composition is particularly suitable for imparting stain release properties to a substrate. Further disclosed are a method of preparation of the fluorochemical composition and a method of treatment of a substrate with the fluorochemical composition.
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机译:本发明公开了一种含氟化合物组合物,其包含二异氰酸酯或三异氰酸酯与至少一种聚醚的缩合产物,所述聚醚可通过使式(I)的含氟化合物取代的环氧化物与式(II)HX1-B-X2H或(III)的化合物反应而获得( R′f′′)kL′2-X2′H其中:B表示通过从式(II)的化合物中除去基团HXα1和HX2′而获得的有机残基。 X 1和X 2各自独立地选自O,NH和S。 L 1表示有机二价连接基团; L 2表示化合价为k + 1的有机连接基团。 k是1至10的整数; R?f? Rf′和Rf′各自独立地选自全氟化和部分氟化的脂族基团; s是0或1; a为0或1。含氟化合物组合物特别适用于赋予基材去污性能。还公开了一种含氟化合物组合物的制备方法和用该含氟化合物组合物处理基材的方法。
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