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Method for preparing water-borne polyurethane antistatic coating materials containing polymer ectrolytes

机译:含有聚合物外溶物的水性聚氨酯抗静电涂料的制备方法

摘要

PURPOSE: Provided is a method for producing an aqueous dispersion polyurethane-based antistatic coating containing polyelectrolyte having excellent transparency and water resistance. CONSTITUTION: The method comprises the steps of (i) reacting polyol and diisocyanate in molecular ratio of 1:2 to form a prepolymer, (ii) neutralizing an ionizable radical of the prepolymer to ionize the prepolymer, (iii) reacting the ionized prepolymer, chain extender and water to form a aqueous dispersion polyurethane having solid content of 40-50 wt%, and (iv) blending the formed dispersion polyurethane, polyelectrolyte and aziridine. The mixing ratio of the polyurethane and polyelectrolyte in the antistatic coating is 5-30 parts by weight of parts with respect to 100 parts by weight of polyurethane(in solids).
机译:用途:提供了一种制备水分散性聚氨酯基抗静电涂料的方法,该涂料包含具有优异的透明度和耐水性的聚电解质。组成:该方法包括以下步骤:(i)使多元醇和二异氰酸酯以1:2的分子比反应形成预聚物,(ii)中和预聚物的可电离基团以使预聚物电离,(iii)使离子化的预聚物反应,扩链剂和水形成固体含量为40-50 wt%的水性分散聚氨酯,以及(iv)将形成的分散聚氨酯,聚电解质和氮丙啶混合。相对于100重量份的聚氨酯(以固体计),抗静电涂层中的聚氨酯和聚电解质的混合比例为5-30重量份。

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