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USE OF TRANSITIONAL METAL COMPLEXES FOR THE FARMING OF KERATED PHASES
USE OF TRANSITIONAL METAL COMPLEXES FOR THE FARMING OF KERATED PHASES
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机译:在过渡相的耕作中使用过渡金属配合物
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摘要
The invention relates to the use of transitional metal (III) complexes of the formula (I), in which UM represents manganese, iron, cobalt, ruthenium, molybdenum or vanadium; R represents an alkylene-, alkenylene-, phenylene- or cycloalkylen- rest which in addition to the substituent X can possibly be substituted with alkyl- and/or aryl-, with a total of between 1 and 12 C atoms, whereby within R the shortest distance between the N-atoms complexing with UM is between 1 and 5 C atoms; X represents -H, -OR3, -NO2, -F, -Cl, -Br or -J; R1, R2 and R3 independently of each other represent hydrogen or an alkyl rest with between 1 and 4 C atoms; Y1 and Y2 independently of each other represent hydrogen or an electron displacing substituent; Z1 and Z2 independently of each other represent hydrogen, -CO2M, -SO3M, -NO2, -CH3, -C2H5, -C3H7, -CH2OH or -CHO; M represents hydrogen or an alkali metal such as lithium, sodium or potassium; and A represents a charge-balancing anion ligand. According to the invention, use of the above complexes allows for a marked reduction in the quantity of oxidizing agent in oxidation dyes. In addition, oxidation dyes can be formulated as oxidizing agents using atmospheric oxygen.
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机译:本发明涉及式(I)的过渡金属(III)配合物的用途,其中UM代表锰,铁,钴,钌,钼或钒; R代表亚烷基,亚烯基,亚苯基或亚环烷基,除取代基X外,R还可以被烷基和/或芳基取代,总共有1至12个碳原子,因此在R中与UM络合的N原子之间的最短距离在1-5个C原子之间; X代表-H,-OR 3,-NO 2,-F,-Cl,-Br或-J; R 1,R 2和R 3彼此独立地表示氢或具有1-4个碳原子的烷基。 Y 1和Y 2彼此独立地表示氢或电子置换性取代基。 Z 1和Z 2彼此独立地表示氢,-CO 2 M,-SO 3 M,-NO 2,-CH 3,-C 2 H 5,-C 3 H 7,-CH 2 OH或-CHO。 M代表氢或碱金属,例如锂,钠或钾; A表示电荷平衡阴离子配体。根据本发明,使用上述配合物可以显着减少氧化染料中氧化剂的量。另外,可以使用大气氧将氧化染料配制成氧化剂。
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