首页> 外国专利> interpolymere from alpha olefin / vinylaromatischem monomers and / or gehindertem aliphatischem or cycloaliphatischem vinylidenmonomeren

interpolymere from alpha olefin / vinylaromatischem monomers and / or gehindertem aliphatischem or cycloaliphatischem vinylidenmonomeren

机译:由α-烯烃/乙烯基芳烃化学单体和/或geehindertem aliphatischem或cycloaliphatischem乙烯基亚单体形成的共聚体

摘要

The present invention relates to alpha -olefin/vinyl aromatic monomer interpolymers with characteristic signals in their carbon 13 NMR spectra. In particular, ethylene/styrene copolymers of the present invention have peaks in the carbon 13 NMR spectra which appear in the chemical shift range 43.70 - 44.25 ppm, preferably from 43.75 - 44.25 ppm and 38.0 - 38.5 ppm, said peaks being at least three times the peak to peak noise. The interpolymers are prepared by polymerizing the appropriate mixture of monomers in the presence of a catalyst such as racemic-(dimethylsilanediyl(2-methyl-4-phenylindenyl)) zirconium dichloride. The polymers of the present invention possess increased modulus as determined from both tensile stress/strain and dynamic mechanical data at comparable vinyl aromatic monomer levels.
机译:本发明涉及在其碳13 NMR光谱中具有特征信号的α-烯烃/乙烯基芳族单体互聚物。特别地,本发明的乙烯/苯乙烯共聚物在碳13 NMR光谱中具有出现在化学位移范围43.70-44.25ppm,优选43.75-44.25ppm和38.0-38.5ppm中的峰,所述峰至少三倍。峰间噪声。通过在催化剂例如外消旋-(二甲基外消旋-(二甲基硅烷二基(2-甲基-4-苯基茚基))二氯化锆)的存在下聚合合适的单体混合物来制备互聚物。本发明的聚合物具有在可比较的乙烯基芳族单体含量下由拉伸应力/应变和动态力学数据确定的增加的模量。

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